0890 100 048 - WURTH DP300 TUBE
Chemwatch Material Safety Data Sheet
Issue Date: 12-Sep-2008
NC317ECP
CHEMWATCH 42214
Version No:4
0890 100 048 - WURTH DP300 TUBE
ADHESIVES
The use of a quantity of material in an unventilated or confined space may result in
increased exposure and an irritating atmosphere developing. Before starting consider
control of exposure by mechanical ventilation. Used on engine gaskets to enhance sealing
quality.
Company: Wurth Pty Ltd
Address:
4 Redwood Drive (abn 48 002 487 096)
Dingley
VIC, 3172
AUS
Telephone: +61 3 9552 9552
Telephone: 1800 331 603
Emergency Tel: 1300 657 765
Fax: +61 3 9551 2994
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC,
and the ADG Code.
None
| RISK | SAFETY |
| Highly flammable. | Keep away from sources of ignition. No smoking. |
| Irritating to eyes. | Avoid contact with eyes. |
| HARMFUL - May cause lung damage if swallowed. | Wear suitable protective clothing. |
| Repeated exposure may cause skin dryness and cracking. | Use only in well ventilated areas. |
| Vapours may cause drowsiness and dizziness. | Keep container in a well ventilated place. |
| Do not empty into drains. | |
| To clean the floor and all objects contaminated by this material use water and detergent. | |
| Keep away from food drink and animal feeding stuffs. | |
| In case of contact with eyes rinse with plenty of water and contact Doctor or Poisons Information Centre. | |
| If swallowed IMMEDIATELY contact Doctor or Poisons Information Centre (show this container or label). | |
| This material and its container must be disposed of as hazardous waste. |
| NAME | CAS RN | % |
| ethyl acetate | 141-78-6 | 20-39 |
| acetone | 67-64-1 | 1-14 |
| silica amorphous | 7631-86-9 | Not Spec^ |
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open
airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
· Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
· Seek medical advice.
If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by
occasionally lifting the upper and lower lids.
· If pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Other measures are usually unnecessary.
for simple esters: -------------------------------------------------------------- BASIC TREATMENT -------------------------------------------------------------- · Establish a patent airway with suction where necessary. · Watch for signs of respiratory insufficiency and assist ventilation as necessary. · Administer oxygen by non-rebreather mask at 10 to 15 l/min. · Monitor and treat, where necessary, for pulmonary oedema . · Monitor and treat, where necessary, for shock. · DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg recommended) for dilution where patient is able to swallow, has a strong gag reflex and does not drool. · Give activated charcoal. -------------------------------------------------------------- ADVANCED TREATMENT -------------------------------------------------------------- · Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred. · Positive-pressure ventilation using a bag-valve mask might be of use. · Monitor and treat, where necessary, for arrhythmias. · Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications. · Drug therapy should be considered for pulmonary oedema. · Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications. · Treat seizures with diazepam. · Proparacaine hydrochloride should be used to assist eye irrigation. -------------------------------------------------------------- EMERGENCY DEPARTMENT -------------------------------------------------------------- · Laboratory analysis of complete blood count, serum electrolytes, BUN, creatinine, glucose, urinalysis, baseline for serum aminotransferases (ALT and AST), calcium, phosphorus and magnesium, may assist in establishing a treatment regime. Other useful analyses include anion and osmolar gaps, arterial blood gases (ABGs), chest radiographs and electrocardiograph. · Positive end-expiratory pressure (PEEP)-assisted ventilation may be required for acute parenchymal injury or adult respiratory distress syndrome. · Consult a toxicologist as necessary. BRONSTEIN, A.C. and CURRANCE, P.L. EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994.
· Alcohol stable foam. · Dry chemical powder. · BCF (where regulations permit). · Carbon dioxide. · Water spray or fog - Large fires only.
· Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. · Consider evacuation (or protect in place). · Fight fire from a safe distance, with adequate cover. · If safe, switch off electrical equipment until vapour fire hazard removed. · Use water delivered as a fine spray to control the fire and cool adjacent area. · Avoid spraying water onto liquid pools. · Do not approach containers suspected to be hot. · Cool fire exposed containers with water spray from a protected location. · If safe to do so, remove containers from path of fire. When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 500 metres in all directions.
· Liquid and vapour are highly flammable. · Severe fire hazard when exposed to heat, flame and/or oxidisers. · Vapour may travel a considerable distance to source of ignition. · Heating may cause expansion or decomposition leading to violent rupture of containers. · On combustion, may emit toxic fumes of carbon monoxide (CO). Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material. Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions.
· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
Breathing apparatus - high vapour/dust levels only.
· Remove all ignition sources. · Clean up all spills immediately. · Avoid breathing vapours and contact with skin and eyes. · Control personal contact by using protective equipment. · Contain and absorb small quantities with vermiculite or other absorbent material. · Wipe up. · Collect residues in a flammable waste container.
· Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. · Consider evacuation (or protect in place). · No smoking, naked lights or ignition sources. · Increase ventilation. · Stop leak if safe to do so. · Water spray or fog may be used to disperse /absorb vapour. · Contain spill with sand, earth or vermiculite. · Use only spark-free shovels and explosion proof equipment. · Collect recoverable product into labelled containers for recycling. · Absorb remaining product with sand, earth or vermiculite. · Collect solid residues and seal in labelled drums for disposal. · Wash area and prevent runoff into drains. · If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· DO NOT enter confined spaces until atmosphere has been checked.
· Avoid smoking, naked lights, heat or ignition sources.
· When handling, DO NOT eat, drink or smoke.
· Vapour may ignite on pumping or pouring due to static electricity.
· DO NOT use plastic buckets.
· Earth and secure metal containers when dispensing or pouring product.
· Use spark-free tools when handling.
· Avoid contact with incompatible materials.
· Keep containers securely sealed.
· Avoid physical damage to containers.
· Always wash hands with soap and water after handling.
· Work clothes should be laundered separately.
· Use good occupational work practice.
· Observe manufacturer's storing and handling recommendations.
· Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.
· Packing as supplied by manufacturer.
· Plastic containers may only be used if approved for flammable liquid.
· Check that containers are clearly labelled and free from leaks.
· For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can
is to be used as an inner package, the can must have a screwed enclosure.
· For materials with a viscosity of at least 2680 cSt. (23 deg. C)
· For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
· Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg. C)
(i) : Removable head packaging;
(ii) : Cans with friction closures and
(iii) : low pressure tubes and cartridges may be used.
· Where combination packages are used, and the inner packages are of glass, there must be sufficient inert
cushioning material in contact with inner and outer packages
· In addition, where inner packagings are glass and contain liquids of packing group I there must be sufficient
inert absorbent to absorb any spillage, unless the outer packaging is a close fitting moulded plastic box and the
substances are not incompatible with the plastic.
· Esters react with acids to liberate heat along with alcohols and acids.
· Strong oxidising acids may cause a vigorous reaction with esters that is sufficiently exothermic to ignite the
reaction products.
· Heat is also generated by the interaction of esters with caustic solutions.
· Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
· Esters may be incompatible with aliphatic amines and nitrates.
· Store in original containers in approved flame-proof area.
· No smoking, naked lights, heat or ignition sources.
· DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
· Keep containers securely sealed.
· Store away from incompatible materials in a cool, dry well ventilated area.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.
| Source | Material | TWA ppm | TWA mg/m³ | STEL ppm | STEL mg/m³ | TWA F/CC |
| __________________ | __________________ | _______ | _______ | _______ | _______ | _______ |
| Australia Exposure Standards | ethyl acetate (Ethyl acetate) | 200 | 720 | 400 | 1440 | |
| Australia Exposure Standards | acetone (Acetone) | 500 | 1185 | 1000 | 2375 | |
| Australia Exposure Standards | silica amorphous (Glasswool) | 0.5 | 0.5 | |||
| Australia Exposure Standards | silica amorphous (Silica - Amorphous Fumed silica (respirable dust)) | 2 | ||||
| Australia Exposure Standards | silica amorphous (Inspirable dust (not otherwise classified)) | 10 | ||||
| Australia Exposure Standards | silica amorphous (Fluorides (as F)) | 2.5 | ||||
| Australia Exposure Standards | silica amorphous (Silica - Amorphous Fume (thermally generated)(respirable dust) (g)) | 2 |
| Material | Revised IDLH Value (mg/m3) | Revised IDLH Value (ppm) |
| ethyl acetate | 2,000 [LEL] | |
| acetone | 2,500 [LEL] |
Not available. Refer to individual constituents.
ETHYL ACETATE: Odour Threshold Value: 6.4-50 ppm (detection), 13.3-75 ppm (recognition) The TLV-TWA provides a significant margin of safety from the standpoint of adverse health effects. Unacclimated subjects found the odour objectionably strong at 200 ppm. Mild nose, eye and throat irritation was experienced at 400 ppm. Workers exposed regularly at concentrations ranging from 375 ppm to 1500 ppm for several months showed no unusual signs or symptoms. ACETONE: Odour Threshold Value: 3.6 ppm (detection), 699 ppm (recognition) Saturation vapour concentration: 237000 ppm @ 20 C NOTE: Detector tubes measuring in excess of 40 ppm, are available. Exposure at or below the recommended TLV-TWA is thought to protect the worker against mild irritation associated with brief exposures and the bioaccumulation, chronic irritation of the respiratory tract and headaches associated with long-term acetone exposures. The NIOSH REL-TWA is substantially lower and has taken into account slight irritation experienced by volunteer subjects at 300 ppm. Mild irritation to acclimatised workers begins at about 750 ppm - unacclimatised subjects will experience irritation at about 350-500 ppm but acclimatisation can occur rapidly. Disagreement between the peak bodies is based largely on the view by ACGIH that widespread use of acetone, without evidence of significant adverse health effects at higher concentrations, allows acceptance of a higher limit. Half-life of acetone in blood is 3 hours which means that no adjustment for shift- length has to be made with reference to the standard 8 hour/day, 40 hours per week because body clearance occurs within any shift with low potential for accumulation. A STEL has been established to prevent excursions of acetone vapours that could cause depression of the central nervous system. Odour Safety Factor(OSF) OSF=38 (ACETONE).
· Safety glasses with side shields. · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
Suitability and durability of glove type is dependent on usage. Factors such as: · frequency and duration of contact, · chemical resistance of glove material, · glove thickness and · dexterity, are important in the selection of gloves. · Wear chemical protective gloves, eg. PVC. · Wear safety footwear or safety gumboots, eg. Rubber.
· Overalls. · PVC Apron. · PVC protective suit may be required if exposure severe. · Eyewash unit. · Ensure there is ready access to a safety shower. · Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce static electricity.
Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important.
| Breathing Zone Level ppm (volume) | Maximum Protection Factor | Half-face Respirator | Full-Face Respirator |
| 1000 | 10 | AX-AUS | - |
| 1000 | 50 | - | AX-AUS |
| 5000 | 50 | Airline * | - |
| 5000 | 100 | - | AX-2 |
| 10000 | 100 | - | AX-3 |
| 100+ | Airline** |
For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilation equipment should be explosion- resistant.
Highly flammable blue liquid with characteristic odour; partly mixes with water.
Liquid.
| Molecular Weight: Not Applicable | Boiling Range (ºC): Not Available |
| Melting Range (ºC): Not Available | Specific Gravity (water=1): ~1.12 |
| Solubility in water (g/L): Partly Miscible | pH (as supplied): Not Available |
| pH (1% solution): Not Available | Vapour Pressure (kPa): 23.3 @ 20C |
| Volatile Component (%vol): Not Available | Evaporation Rate: Not Available |
| Relative Vapour Density (air=1): >1 | Flash Point (ºC): -5 |
| Lower Explosive Limit (%): Not Available | Upper Explosive Limit (%): Not Available |
| Autoignition Temp (ºC): Not Available | Decomposition Temp (ºC): Not Available |
| State: Liquid | Viscosity: Not Available |
· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.
Swallowing of the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis; serious consequences may result. (ICSC13733).
This material can cause eye irritation and damage in some persons. The liquid produces a high level of eye discomfort and is capable of causing pain and severe conjunctivitis. Corneal injury may develop, with possible permanent impairment of vision, if not promptly and adequately treated.
Repeated exposure may cause skin cracking, flaking or drying following normal handling and use. Open cuts, abraded or irritated skin should not be exposed to this material. Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack of co-ordination, and vertigo. Inhalation hazard is increased at higher temperatures.
Prolonged or repeated skin contact may cause drying with cracking, irritation and possible dermatitis following. As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice.
Not available. Refer to individual constituents. ETHYL ACETATE: unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
| TOXICITY | IRRITATION |
| Oral (rat) LD50: 5620 mg/kg | Eye (human): 400 ppm |
| Inhalation (rat) LC50: 1600 ppm/8h | |
| Inhalation (human) TCLo: 400 ppm | |
| Inhalation (Human) TCLo: 400 ppm/4h | |
| Oral (Mouse) LD50: 4100 mg/kg | |
| Intraperitoneal (Mouse) LD50: 709 mg/kg | |
| Oral (Rabbit) LD50: 4935 mg/kg | |
| Oral (Guinea) pig: LD50 5500 mg/kg |
| TOXICITY | IRRITATION |
| Oral (man) TDLo: 2857 mg/kg | Eye (human): 500 ppm - Irritant |
| Oral (rat) LD50: 5800 mg/kg | Eye (rabbit): 3.95 mg - SEVERE |
| Inhalation (human) TCLo: 500 ppm | Eye (rabbit): 20mg/24hr -Moderate |
| Inhalation (man) TCLo: 12000 ppm/4 hr | Skin (rabbit):395mg (open) - Mild |
| Inhalation (man) TCLo: 10 mg/m³/6 hr | Skin (rabbit): 500 mg/24hr - Mild |
| Inhalation (rat) LC50: 50100 mg/m³/8 hr | |
| Dermal (rabbit) LD50: 20000 mg/kg |
Marine Pollutant: Not Determined DO NOT discharge into sewer or waterways. WGK: Classification in accordance with German Water Resources Act. Water hazard class 1: slightly hazardous to water. [Wurth] Refer to data for ingredients, which follows: ETHYL ACETATE: log Pow (Verschueren 1983): 0.66/0.73 ThOD: 50.4 log Pow (Verschueren 1983): 0.66/0.73 BOD5: 15% COD: 1.54 (83%) ThOD: 1.82 Half- life Soil - High (hours): 168 Half- life Soil - Low (hours): 24 Half- life Air - High (hours): 353 Half- life Air - Low (hours): 35.3 Half- life Surface water - High (hours): 168 Half- life Surface water - Low (hours): 24 Half- life Ground water - High (hours): 336 Half- life Ground water - Low (hours): 48 Aqueous biodegradation - Aerobic - High (hours): 168 Aqueous biodegradation - Aerobic - Low (hours): 24 Aqueous biodegradation - Anaerobic - High (hours): 672 Aqueous biodegradation - Anaerobic - Low (hours): 96 Aqueous biodegradation - Removal secondary treatment - High (hours): 96% Aqueous biodegradation - Removal secondary treatment - Low (hours): 99.90% Photooxidation half- life water - High (hours): 9.60E+05 Photooxidation half- life water - Low (hours): 24090 Photooxidation half- life air - High (hours): 353 Photooxidation half- life air - Low (hours): 35.3 First order hydrolysis half- life (hours): 1.77E+04 Acid rate constant [M(H+)- HR]- 1: 3.05E- 08 Base rate constant [MOH)- HR]- 1: 2.99E- 05 DO NOT discharge into sewer or waterways. log Kow: 0.66-0.73 Half-life (hr) air: 200 Half-life (hr) H2O surface water: 10 Henry's atm m³ /mol: 1.20E-04 BOD 5 if unstated: 0.1-1.24,16-36% COD: 1.54,83% ThOD: 1.82 ACETONE: Fish LC50 (96hr.) (mg/l): 8300- 40000 Daphnia magna EC50 (48hr.) (mg/l): 10 log Kow (Prager 1995): - 0.24 log Kow (Sangster 1997): - 0.24 log Pow (Verschueren 1983): - 0.24 BOD5: 122% ThOD: 72 Half- life Soil - High (hours): 168 Half- life Soil - Low (hours): 24 Half- life Air - High (hours): 2790 Half- life Air - Low (hours): 279 Half- life Surface water - High (hours): 168 Half- life Surface water - Low (hours): 24 Half- life Ground water - High (hours): 336 Half- life Ground water - Low (hours): 48 Aqueous biodegradation - Aerobic - High (hours): 168 Aqueous biodegradation - Aerobic - Low (hours): 24 Aqueous biodegradation - Anaerobic - High (hours): 672 Aqueous biodegradation - Anaerobic - Low (hours): 96 Aqueous biodegradation - Removal secondary treatment - High (hours): 75% Aqueous biodegradation - Removal secondary treatment - Low (hours): 54% Aqueous photolysis half- life - High (hours): 270 Photooxidation half- life water - High (hours): 3.97E+06 Photooxidation half- life water - Low (hours): 9.92E+04 Photooxidation half- life air - High (hours): 2790 Photooxidation half- life air - Low (hours): 279 Ketones are generally not degraded by hydrolysis. Based on its reactions in air, it seems likely that they undergo photolysis in water. It is probable that ketones will be biodegraded to an appreciable degree by micro-organisms in soil and water. They are unlikely to bioconcentrate or biomagnify. for acetone: log Kow: -0.24 Half-life (hr) air: 312-1896 Half-life (hr) H2O surface water: 20 Henry's atm m3 /mol: 3.67E-05 BOD 5: 0.31-1.76,46-55% COD: 1.12-2.07 ThOD: 2.2 BCF: 0.69 Environmental fate: Acetone preferentially locates in the air compartment when released to the environment. A substantial amount of acetone can also be found in water, which is consistent with the high water to air partition coefficient and its small, but detectable, presence in rain water, sea water, and lake water samples. Very little acetone is expected to reside in soil, biota, or suspended solids. This is entirely consistent with the physical and chemical properties of acetone and with measurements showing a low propensity for soil absorption and a high preference for moving through the soil and into the ground water In air, acetone is lost by photolysis and reaction with photochemically produced hydroxyl radicals; the estimated half-life of these combined processes is about 22 days. The relatively long half-life allows acetone to be transported long distances from its emission source. Acetone is highly soluble and slightly persistent in water, with a half-life of about 20 hours; it is minimally toxic to aquatic life. Acetone released to soil volatilises although some may leach into the ground where it rapidly biodegrades. Acetone does not concentrate in the food chain. Acetone meets the OECD definition of readily biodegradable which requires that the biological oxygen demand (BOD) is at least 70% of the theoretical oxygen demand (THOD) within the 28-day test period Drinking Water Standard: none available. Soil Guidelines: none available. Air Quality Standards: none available. Ecotoxicity: Testing shows that acetone exhibits a low order of toxicity Fish LC50: brook trout 6070 mg/l; fathead minnow 15000 mg/l Bird LC0 (5 day): Japanese quail, ring-neck pheasant 40,000 mg/l Daphnia magna LC50 (48 h): 15800 mg/l; NOEC 8500 mg/l Aquatic invertebrate 2100 - 16700 mg/l Aquatic plant NOEC: 5400-7500 mg/l Daphnia magna chronic NOEC 1660 mg/l Acetone vapors were shown to be relatively toxic to two types insects and their eggs. The time to 50% lethality (LT50) was found to be 51.2 hr and 67.9 hr when the flour beetle (Tribolium confusum) and the flour moth (Ephestia kuehniella) were exposed to an airborne acetone concentration of 61.5 mg/m3. The LT50 values for the eggs were 30-50% lower than for the adult. The direct application of acetone liquid to the body of the insects or surface of the eggs did not, however, cause any mortality. The ability of acetone to inhibit cell multiplication has been examined in a wide variety of microorganisms. The results have generally indicated mild to minimal toxicity with NOECs greater than 1700 mg/L for exposures lasting from 6 hr to 4 days. Longer exposure periods of 7 to 8 days with bacteria produced mixed results; but overall the data indicate a low degree of toxicity for acetone. The only exception to these findings were the results obtained with the flagellated protozoa (Entosiphon sulcatum) which yielded a 3-day NOEC of 28 mg/L. DO NOT discharge into sewer or waterways.
· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste
management authority for disposal if no suitable treatment or disposal facility can be
identified.
· Dispose of by: Burial in a licenced land-fill or Incineration in a licenced apparatus
(after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are
cleaned and destroyed.
Labels Required: FLAMMABLE LIQUID HAZCHEM: 3[Y]E UNDG:
| Dangerous Goods Class: | 3 | Subrisk: | None |
| UN Number: | 1133 | Packing Group: | II |
| ICAO/IATA Class: | 3 | ICAO/IATA Subrisk: | None |
| UN/ID Number: | 1133 | Packing Group: | II |
| Special provisions: | A3 |
| IMDG Class: | 3 | IMDG Subrisk: | None |
| UN Number: | 1133 | Packing Group: | II |
| EMS Number: | F-E,S-D | Special provisions: | 944 |
| Limited Quantities: | 5 L | Marine Pollutant: | Not Determined |
0890 100 048 - Wurth DP300 Tube (CAS: None):
No regulations applicable
ethyl acetate (CAS: 141-78-6) is found on the following regulatory lists;
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
GESAMP/EHS Composite List of Hazard Profiles - Hazard evaluation of substances transported by ships
IMO IBC Code Chapter 17: Summary of minimum requirements
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Air Transport Association (IATA) Dangerous Goods Regulations
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
acetone (CAS: 67-64-1) is found on the following regulatory lists;
Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 2
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Illicit Drug Reagents/Essential Chemicals - Category III
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
GESAMP/EHS Composite List of Hazard Profiles - Hazard evaluation of substances transported by ships
IMO IBC Code Chapter 18: List of products to which the Code does not apply
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Air Transport Association (IATA) Dangerous Goods Regulations
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II
United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International Control -
Table II
| Ingredient Name | CAS |
| silica amorphous | 7631-86-9, 112945-52-5 |
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk
Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Scale of use, frequency of use and current or available engineering controls must be
considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 12-Sep-2008
Print Date: 16-Sep-2008