0890 100 11 - WURTH ADHESIVE & SEALING COMPOUND WHITE
Chemwatch Material Safety Data Sheet
Issue Date: 12-Sep-2008
NC317ECP
CHEMWATCH 7503-07
Version No:4
0890 100 11 - WURTH ADHESIVE & SEALING COMPOUND WHITE
sealant
Sealant.
Company: Wurth Pty Ltd
Address:
4 Redwood Drive (abn 48 002 487 096)
Dingley
VIC, 3172
AUS
Telephone: +61 3 9552 9552
Telephone: 1800 331 603
Emergency Tel: 1300 657 765
Fax: +61 3 9551 2994
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.
None
| RISK | SAFETY |
| None under normal operating conditions. | Avoid contact with skin. |
| Use only in well ventilated areas. | |
| Keep container in a well ventilated place. |
| NAME | CAS RN | % |
| xylene | 1330-20-7 | 1-12.4 |
| titanium dioxide | 13463-67-7 | 1-10 |
| distillates, petroleum, light, hydrotreated | 64742-47-8 | 1-5 |
| calcium oxide | 1305-78-8 | 1-4^ |
| calcium dihydroxide | Not Spec | |
| polyvinyl chloride | 9002-86-2 | Not Spec^ |
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open
airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
· Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
· Seek medical advice.
If this product comes in contact with eyes:
· Wash out immediately with water.
· If irritation continues, seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin or hair contact occurs:
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Other measures are usually unnecessary.
For acute or short term repeated exposures to xylene: · Gastro-intestinal absorption is significant with ingestions. For ingestions exceeding 1-2 ml (xylene)/kg, intubation and lavage with cuffed endotracheal tube is recommended. The use of charcoal and cathartics is equivocal. · Pulmonary absorption is rapid with about 60-65% retained at rest. · Primary threat to life from ingestion and/or inhalation, is respiratory failure. · Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 < 50 mm Hg or pCO2 > 50 mm Hg) should be intubated. · Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves clearance. · A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of pneumothorax. · Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation to catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a second choice. BIOLOGICAL EXPOSURE INDEX - BEI These represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV):
| Determinant | Index | Sampling Time | Comments |
| Methylhippu-ric acids in urine | 1.5 gm/gm creatinine | End of shift | |
| 2 mg/min | Last 4 hrs of shift |
· Foam. · Dry chemical powder. · BCF (where regulations permit). · Carbon dioxide. · Water spray or fog - Large fires only.
· Alert Fire Brigade and tell them location and nature of hazard. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water courses. · Use water delivered as a fine spray to control fire and cool adjacent area. · DO NOT approach containers suspected to be hot. · Cool fire exposed containers with water spray from a protected location. · If safe to do so, remove containers from path of fire. · Equipment should be thoroughly decontaminated after use.
Combustible. Will burn if ignited. Combustion products include: carbon dioxide (CO2), hydrogen chloride, phosgene, other pyrolysis products typical of burning organic material, carbon monoxide (CO). May emit poisonous fumes.
· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
· Clean up all spills immediately. · Avoid contact with skin and eyes. · Wear impervious gloves and safety goggles. · Trowel up/scrape up. · Place spilled material in clean, dry, sealed container. · Flush spill area with water.
Minor hazard. · Clear area of personnel. · Alert Fire Brigade and tell them location and nature of hazard. · Control personal contact by using protective equipment as required. · Prevent spillage from entering drains or water ways. · Contain spill with sand, earth or vermiculite. · Collect recoverable product into labelled containers for recycling. · Absorb remaining product with sand, earth or vermiculite and place in appropriate containers for disposal. · Wash area and prevent runoff into drains or waterways. · If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· DO NOT enter confined spaces until atmosphere has been checked.
· DO NOT allow material to contact humans, exposed food or food utensils.
· Avoid contact with incompatible materials.
· When handling, DO NOT eat, drink or smoke.
· Keep containers securely sealed when not in use.
· Avoid physical damage to containers.
· Always wash hands with soap and water after handling.
· Work clothes should be laundered separately. Launder contaminated clothing before re-use.
· Use good occupational work practice.
· Observe manufacturer's storing and handling recommendations.
· Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions
are maintained.
· Metal can or drum
· Packaging as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.
· Avoid reaction with oxidising agents.
· NOTE: May develop pressure in containers; open carefully. Vent periodically.
· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.
| Source | Material | TWA ppm | TWA mg/m³ | STEL ppm | STEL mg/m³ |
| __________________ | __________________ | _______ | _______ | _______ | _______ |
| Australia Exposure Standards | xylene (Xylene (o-, m-, p- isomers)) | 80 | 350 | 150 | 655 |
| Australia Exposure Standards | titanium dioxide (Titanium dioxide (a)) | 10 | |||
| Australia Exposure Standards | calcium oxide (Calcium oxide) | 2 | |||
| Australia Exposure Standards | polyvinyl chloride (Inspirable dust (not otherwise classified)) | 10 |
| • distillates, petroleum, light, hydrotreated: | CAS:64742-47-8 |
| Material | Revised IDLH Value (mg/m3) | Revised IDLH Value (ppm) |
| xylene | 900 | |
| titanium dioxide | 5,000 |
Not available. Refer to individual constituents.
DISTILLATES, PETROLEUM, LIGHT, HYDROTREATED: TITANIUM DIOXIDE: Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no- observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach, typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five- category system based on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to that of the USA. OSHA (USA) concluded that exposure to sensory irritants can: · cause inflammation · cause increased susceptibility to other irritants and infectious agents · lead to permanent injury or dysfunction · permit greater absorption of hazardous substances and · acclimate the worker to the irritant warning properties of these substances thus increasing the risk of overexposure. TITANIUM DIOXIDE: WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans. Animal studies at 10 mg/m3 show no significant fibrosis, possibly reversible tissue reaction and the architecture of lung air spaces remains intact. DISTILLATES, PETROLEUM, LIGHT, HYDROTREATED: for petroleum distillates: CEL TWA: 500 ppm, 2000 mg/m3 (compare OSHA TWA). ES TWA: 5 mg/m3 refined mineral oil mist. Human exposure to oil mist alone has not been demonstrated to cause health effects except at levels above 5 mg/m3 (this applies to particulates sampled by a method that does not collect vapour). It is not advisable to apply this standard to oils containing unknown concentrations and types of additive. CEL TWA: 300 ppm, 2100 mg/m3
· Safety glasses with side shields · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
· Wear chemical protective gloves, eg. PVC. · Wear safety footwear or safety gumboots, eg. Rubber.
· Overalls. · P.V.C. apron. · Barrier cream. · Skin cleansing cream. · Eye wash unit.
Respiratory protection may be required when ANY "Worst Case" vapour-phase concentration is exceeded (see Computer Prediction in "Exposure Standards")
| Protection Factor (Min) | Half-Face Respirator | Full-Face Respirator | |
| 10 x ES | Air-line* | A--2 | |
| - | A--PAPR-2 | ||
| 20 x ES | - | A--3 | |
| 20+ x ES | - | Air-line** | |
General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas.
White paste with a slight odour; reacts with water.
| Molecular Weight: Not Applicable | Boiling Range (ºC): Not Available |
| Melting Range (ºC): Not Available | Specific Gravity (water=1): 1.17 |
| Solubility in water (g/L): Reacts | pH (as supplied): Not Applicable |
| pH (1% solution): Not Applicable | Vapour Pressure (kPa): <=110 @ 50C |
| Volatile Component (%vol): Not Available | Evaporation Rate: Not Available |
| Relative Vapour Density (air=1): Not Available | Flash Point (ºC): 40-55 |
| Lower Explosive Limit (%): Not Available | Upper Explosive Limit (%): Not Available |
| Autoignition Temp (ºC): >200 | Decomposition Temp (ºC): Not Available |
| State: Non Slump Paste | Viscosity: Not Available |
Product is considered stable and hazardous polymerisation will not occur.
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual, following ingestion, especially where pre- existing organ (eg. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant quantities is not thought to be cause for concern.
Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with windburn).
The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Open cuts, abraded or irritated skin should not be exposed to this material. Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. Headache, fatigue, tiredness, irritability and digestive disturbances (nausea, loss of appetite and bloating) are the most common symptoms of xylene overexposure. Injury to the heart, liver, kidneys and nervous system has also been noted amongst workers. Temporary memory loss, kidney impairment, temporary confusion and some evidence of disturbance of liver function was reported in workers grossly exposed to xylene (1%). One death was noted, with autopsy revealing lung congestion, oedema and local bleeding of alveoli. Inhaling xylene at 100 ppm for 5-6 hours can increase reaction time and cause slight inco-ordination. Tolerance developed during the work week, but was lost over the weekend. Physical exercise may reduce tolerance. About 4-8% of total absorbed xylene accumulates in fat.
Women exposed to xylene in the first 3 months of pregnancy showed a slightly increased risk of miscarriage and birth defects. Evaluation of workers chronically exposed to xylene has demonstrated lack of genetic toxicity. Exposure to xylene has been associated with increased rates of blood cancer, but this may be complicated by exposure to other substances, including benzene. Animal testing found no evidence of cancer-causing activity. Repeated application of mildly hydrotreated oils (principally paraffinic), to mouse skin, induced skin tumours; no tumours were induced with severely hydrotreated oils.
Not available. Refer to individual constituents. XYLENE: unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
| TOXICITY | IRRITATION |
| Oral (human) LDLo: 50 mg/kg | Skin (rabbit):500 mg/24h Moderate |
| Oral (rat) LD50: 4300 mg/kg | Eye (human): 200 ppm Irritant |
| Inhalation (human) TCLo: 200 ppm | Eye (rabbit): 87 mg Mild |
| Inhalation (man) LCLo: 10000 ppm/6h | Eye (rabbit): 5 mg/24h SEVERE |
| Inhalation (rat) LC50: 5000 ppm/4h | |
| Oral (Human) LD: 50 mg/kg | |
| Inhalation (Human) TCLo: 200 ppm/4h | |
| Intraperitoneal (Rat) LD50: 2459 mg/kg | |
| Subcutaneous (Rat) LD50: 1700 mg/kg | |
| Oral (Mouse) LD50: 2119 mg/kg | |
| Intraperitoneal (Mouse) LD50: 1548 mg/kg | |
| Intravenous (Rabbit) LD: 129 mg/kg | |
| Inhalation (Guinea) pig: LC 450 ppm/4h |
| TOXICITY | IRRITATION |
| Skin (human) 0.3: mg/3d-I Mild |
| MATERIAL | CARCINOGEN | REPROTOXIN | SENSITISER | SKIN |
| _______________ | ____________ | __________ | __________ | __________ |
| xylene | IARC:3 | ILOEl | ||
| titanium dioxide | IARC:2B |
DO NOT discharge into sewer or waterways. WGK: Classification in accordance with German Water Resources Act. Water hazard class 2: hazardous to water. [Wurth] Refer to data for ingredients, which follows: XYLENE: Fish LC50 (96hr.) (mg/l): 13.5 BCF<100: 2.14- 2.20 log Kow (Prager 1995): 3.12- 3.20 Half- life Soil - High (hours): 672 Half- life Soil - Low (hours): 168 Half- life Air - High (hours): 44 Half- life Air - Low (hours): 2.6 Half- life Surface water - High (hours): 672 Half- life Surface water - Low (hours): 168 Half- life Ground water - High (hours): 8640 Half- life Ground water - Low (hours): 336 Aqueous biodegradation - Aerobic - High (hours): 672 Aqueous biodegradation - Aerobic - Low (hours): 168 Aqueous biodegradation - Anaerobic - High (hours): 8640 Aqueous biodegradation - Anaerobic - Low (hours): 4320 Photolysis maximum light absorption - High (nano- m): 269.5 Photolysis maximum light absorption - Low (nano- m): 265 Photooxidation half- life water - High (hours): 2.70E+08 Photooxidation half- life water - Low (hours): 3.90E+05 Photooxidation half- life air - High (hours): 44 Photooxidation half- life air - Low (hours): 2.6 DO NOT discharge into sewer or waterways. TITANIUM DIOXIDE: DO NOT discharge into sewer or waterways. DISTILLATES, PETROLEUM, LIGHT, HYDROTREATED: The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of waters after release in calm sea conditions. This is expected to evaporate and enter the atmosphere where it will be degraded through reaction with hydroxy radicals. Some of the material will become associated with benthic sediments, and it is likely to be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or anaerobic. The material, in probability, is biodegradable, under aerobic conditions (isomerised olefins and alkenes show variable results). Evidence also suggests that the hydrocarbons may be degradable under anaerobic conditions although such degradation in benthic sediments may be a relatively slow process. Under aerobic conditions the material will degrade to water and carbon dioxide, while under anaerobic processes it will produce water, methane and carbon dioxide. Based on test results, as well as theoretical considerations, the potential for bioaccumulation may be high. Toxic effects are often observed in species such as blue mussel, daphnia, freshwater green algae, marine copepods and amphipods. Alkenes have low log octanol/water partition coefficients (Kow) of about 1 and estimated bioconcentration factors (BCF) of about 10; aromatics have intermediate values (log Kow values of 2-3 and BCF values of 20-200), while C5 and greater alkanes have fairly high values (log Kow values of about 3-4.5 and BCF values of 100-1,500 The estimated volatilisation half-lives for alkanes and benzene, toluene, ethylbenzene, xylene (BTEX) components were predicted as 7 days in ponds, 1.5 days in rivers, and 6 days in lakes. The volatilisation rate of naphthalene and its substituted derivatives were estimated to be slower Indigenous microbes found in many natural settings (e.g., soils, groundwater, ponds) have been shown to be capable of degrading organic compounds. Unlike other fate processes that disperse contaminants in the environment, biodegradation can eliminate the contaminants without transferring them across media. The final products of microbial degradation are carbon dioxide, water, and microbial biomass. The rate of hydrocarbon degradation depends on the chemical composition of the product released to the environment as well as site-specific environmental factors. Generally the straight chain hydrocarbons and the aromatics are degraded more readily than the highly branched aliphatic compounds. The n-alkanes, n-alkyl aromatics, and the aromatics in the C10-C22 range are the most readily biodegradable; n-alkanes, n-alkyl aromatics, and aromatics in the C5-C9 range are biodegradable at low concentrations by some microorganisms, but are generally preferentially removed by volatilisation and thus are unavailable in most environments; n-alkanes in the C1-C4 ranges are biodegradable only by a narrow range of specialised hydrocarbon degraders; and n-alkanes, n-alkyl aromatics, and aromatics above C22 are generally not available to degrading microorganisms. Hydrocarbons with condensed ring structures, such as PAHs with four or more rings, have been shown to be relatively resistant to biodegradation. PAHs with only 2 or 3 rings (e.g., naphthalene, anthracene) are more easily biodegraded. PAHs with only 2 or 3 rings (e.g., naphthalene, anthracene) are more easily biodegraded. In almost all cases, the presence of oxygen is essential for effective biodegradation of oil. The ideal pH range to promote biodegradation is close to neutral (6-8). For most species, the optimal pH is slightly alkaline, that is, greater than 7. All biological transformations are affected by temperature. Generally, as the temperature increases, biological activity tends to increase up to a temperature where enzyme denaturation occurs. Atmospheric fate: Alkanes, isoalkanes, and cycloalkanes have half-lives on the order of 1- 10 days, whereas alkenes, cycloalkenes, and substituted benzenes have half-lives of 1 day or less. Photochemical oxidation products include aldehydes, hydroxy compounds, nitro compounds, and peroxyacyl nitrates. Alkenes, certain substituted aromatics, and naphthalene are potentially susceptible to direct photolysis. Drinking Water Standards: hydrocarbon total: 10 ug/l (UK max.). DO NOT discharge into sewer or waterways.
· Recycle wherever possible or consult manufacturer for recycling options.
· Consult State Land Waste Authority for disposal.
· Bury or incinerate residue at an approved site.
· Recycle containers if possible, or dispose of in an authorised landfill.
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG
0890 100 11 - Wurth Adhesive & Sealing Compound White (CAS: None):
No regulations applicable
xylene (CAS: 1330-20-7) is found on the following regulatory lists;
Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - organic compounds)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Domestic water quality
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix I
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
GESAMP/EHS Composite List of Hazard Profiles - Hazard evaluation of substances transported by ships
IMO IBC Code Chapter 17: Summary of minimum requirements
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
IMO Provisional Categorization of Liquid Substances - List 1: Pure or technically pure products
International Agency for Research on Cancer (IARC) Carcinogens
International Air Transport Association (IATA) Dangerous Goods Regulations
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water
titanium dioxide (CAS: 13463-67-7) is found on the following regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 4
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines
Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products
CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP
IMO IBC Code Chapter 17: Summary of minimum requirements
International Agency for Research on Cancer (IARC) Carcinogens
OECD Representative List of High Production Volume (HPV) Chemicals
titanium dioxide (CAS: 1317-70-0) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
titanium dioxide (CAS: 1317-80-2) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 4
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
GESAMP/EHS Composite List of Hazard Profiles - Hazard evaluation of substances transported by ships
OECD Representative List of High Production Volume (HPV) Chemicals
distillates, petroleum, light, hydrotreated (CAS: 64742-47-8) is found on the following regulatory lists;
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
International Air Transport Association (IATA) Dangerous Goods Regulations
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
No data available for titanium dioxide as CAS: 12188-41-9.
| Ingredient Name | CAS |
| titanium dioxide | 13463-67-7, 1317-70-0, 1317-80-2, 12188-41-9 |
Ingredient ORG UF Endpoint CR Adeq
TLV
xylene 1.5 mg/m3 10 D NA -
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time-
weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m3): 2100 mg/m³
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m³) (%)
distillates, petroleum, light, hydrotreated 300.00 2100.0000 5.0
Operations which produce a spray/mist or fume/dust, introduce particulates to the
breathing zone.
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
At the "Composite Exposure Standard for Mixture" (TWA) (mg/m3): 2100 mg/m³
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk
Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Scale of use, frequency of use and current or available engineering controls must be
considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 12-Sep-2008
Print Date: 16-Sep-2008