0890 100 31 - WURTH ADHESIVE & SEALING COMPOUND BLACK
Chemwatch Material Safety Data Sheet
Issue Date: 24-Mar-2009
NC317ECP
CHEMWATCH 7503-09
Version No:4
0890 100 31 - WURTH ADHESIVE & SEALING COMPOUND BLACK
"Manufacturer's Code: 0890 100 31"
Sealant.
Company: Wurth Pty Ltd
Address:
4 Redwood Drive (abn 48 002 487 096)
Dingley
VIC, 3172
AUS
Telephone: +61 3 9552 9552
Telephone: 1800 331 603
Emergency Tel: 1300 657 765
Fax: +61 3 9551 2994
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the
ADG Code.
None
| RISK | SAFETY |
| » Harmful to aquatic organisms may cause long-term adverse effects in the aquatic environment. | » Avoid exposure - obtain special instructions before use. |
| NAME | CAS RN | % |
| xylene | 1330-20-7 | 1-12 |
| distillates, petroleum, light, hydrotreated | 64742-47-8 | 1-5 |
| calcium oxide | 1305-78-8 | 1-4 |
| bis(1, 2, 2, 6, 6- pentamethyl- 4- piperidyl)sebacate | 41556-26-7 | 0.25-0.4^ |
| methyl 1, 2, 2, 6, 6- pentamethyl- 4- piperidyl sebacate | 82919-37-7 | 0.1-0.9^ |
| calcium hydroxide | 1305-62-0 | NotSpec^ |
| butyl benzyl phthalate | 85-68-7 | 0.25-0.4^ |
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
· Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
· Seek medical advice.
» If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
· If pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
» If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Other measures are usually unnecessary.
» Treat symptomatically.
· Foam. · Dry chemical powder. · BCF (where regulations permit). · Carbon dioxide. · Water spray or fog - Large fires only.
· Alert Fire Brigade and tell them location and nature of hazard. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water courses. · Use water delivered as a fine spray to control fire and cool adjacent area. · DO NOT approach containers suspected to be hot. · Cool fire exposed containers with water spray from a protected location. · If safe to do so, remove containers from path of fire. · Equipment should be thoroughly decontaminated after use.
· Combustible. · Slight fire hazard when exposed to heat or flame. · Heating may cause expansion or decomposition leading to violent rupture of containers. · On combustion, may emit toxic fumes of carbon monoxide (CO). · May emit acrid smoke. · Mists containing combustible materials may be explosive. Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
· Clean up all spills immediately. · Avoid contact with skin and eyes. · Wear impervious gloves and safety goggles. · Trowel up/scrape up. · Place spilled material in clean, dry, sealed container. · Flush spill area with water.
· Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. · Stop leak if safe to do so. · Contain spill with sand, earth or vermiculite. · Collect recoverable product into labelled containers for recycling. · Neutralise/decontaminate residue. · Collect solid residues and seal in labelled drums for disposal. · Wash area and prevent runoff into drains. · After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. · If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· DO NOT enter confined spaces until atmosphere has been checked.
· DO NOT allow material to contact humans, exposed food or food utensils.
· Avoid contact with incompatible materials.
· When handling, DO NOT eat, drink or smoke.
· Keep containers securely sealed when not in use.
· Avoid physical damage to containers.
· Always wash hands with soap and water after handling.
· Work clothes should be laundered separately. Launder contaminated clothing before re-use.
· Use good occupational work practice.
· Observe manufacturer's storing and handling recommendations.
· Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.
· Metal can or drum
· Packaging as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.
· Avoid reaction with oxidising agents.
· Avoid strong acids, acid chlorides and acid anhydrides..
· Avoid strong bases.
· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.
| Source | Material | TWA ppm | TWA mg/m³ | STEL ppm | STEL mg/m³ |
| ___________ | ___________ | _______ | _______ | _______ | _______ |
| Australia Exposure Standards | xylene (Xylene (o-, m-, p- isomers)) | 80 | 350 | 150 | 655 |
| Australia Exposure Standards | distillates, petroleum, light, hydrotreated (Oil mist, refined mineral) | 5 | |||
| Australia Exposure Standards | calcium oxide (Calcium oxide) | 2 | |||
| Australia Exposure Standards | calcium hydroxide (Calcium hydroxide) | 5 |
The following materials had no OELs on our records
| • bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate: | CAS:41556-26-7 |
| • methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate: | CAS:82919-37-7 |
| • butyl benzyl phthalate: | CAS:85-68-7 |
| Material | Revised IDLH Value (mg/m3) | Revised IDLH Value (ppm) |
| xylene | 900 | |
| calcium oxide | 25 |
» Not available. Refer to individual constituents.
XYLENE: » for xylenes: IDLH Level: 900 ppm Odour Threshold Value: 20 ppm (detection), 40 ppm (recognition) NOTE: Detector tubes for o-xylene, measuring in excess of 10 ppm, are available commercially. (m-xylene and p-xylene give almost the same response). Xylene vapour is an irritant to the eyes, mucous membranes and skin and causes narcosis at high concentrations. Exposure to doses sufficiently high to produce intoxication and unconsciousness also produces transient liver and kidney toxicity. Neurologic impairment is NOT evident amongst volunteers inhaling up to 400 ppm though complaints of ocular and upper respiratory tract irritation occur at 200 ppm for 3 to 5 minutes. Exposure to xylene at or below the recommended TLV-TWA and STEL is thought to minimise the risk of irritant effects and to produce neither significant narcosis or chronic injury. An earlier skin notation was deleted because percutaneous absorption is gradual and protracted and does not substantially contribute to the dose received by inhalation. Odour Safety Factor(OSF) OSF=4 (XYLENE). DISTILLATES, PETROLEUM, LIGHT, HYDROTREATED: » Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach, typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category system based on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to that of the USA. OSHA (USA) concluded that exposure to sensory irritants can: · cause inflammation · cause increased susceptibility to other irritants and infectious agents · lead to permanent injury or dysfunction · permit greater absorption of hazardous substances and · acclimate the worker to the irritant warning properties of these substances thus increasing the risk of overexposure. for petroleum distillates: CEL TWA: 500 ppm, 2000 mg/m3 (compare OSHA TWA). ES TWA: 5 mg/m3 refined mineral oil mist. Human exposure to oil mist alone has not been demonstrated to cause health effects except at levels above 5 mg/m3 (this applies to particulates sampled by a method that does not collect vapour). It is not advisable to apply this standard to oils containing unknown concentrations and types of additive. CEL TWA: 300 ppm, 2100 mg/m3 CALCIUM OXIDE: The TLV-TWA is thought to be protective against undue irritation and is analogous to that recommended for sodium hydroxide.
· Safety glasses with side shields · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
· Wear chemical protective gloves, eg. PVC. · Wear safety footwear or safety gumboots, eg. Rubber.
· Overalls. · P.V.C. apron. · Barrier cream. · Skin cleansing cream. · Eye wash unit.
» Respiratory protection may be required when ANY "Worst Case" vapour-phase concentration is exceeded (see Computer Prediction in "Exposure Standards")
| Protection Factor (Min) | Half-Face Respirator | Full-Face Respirator | |
| 10 x ES | Air-line* | A-P--2 | |
| - | A-P--PAPR-2 | ||
| 20 x ES | - | A-P--3 | |
| 20+ x ES | - | Air-line** | |
» General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas.
Black paste with a slight odour; reacts with water.
| Molecular Weight: Not Applicable | Boiling Range (ºC): Not Available |
| Melting Range (ºC): Not Available | Specific Gravity (water=1): 1.17 |
| Solubility in water (g/L): Reacts | pH (as supplied): Not Applicable |
| pH (1% solution): Not Applicable | Vapour Pressure (kPa): <110 @ 50C |
| Volatile Component (%vol): Not Available | Evaporation Rate: Not Available |
| Relative Vapour Density (air=1): Not Available | Flash Point (ºC): 40-55 |
| Lower Explosive Limit (%): Not Available | Upper Explosive Limit (%): Not Available |
| Autoignition Temp (ºC): >200 | Decomposition Temp (ºC): Not Available |
| State: Non Slump Paste | Viscosity: Not Available |
» Product is considered stable and hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
» Considered an unlikely route of entry in commercial/industrial environments. Ingestion may result in nausea, abdominal irritation, pain and vomiting.
» The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.
» The material may accentuate any pre-existing dermatitis condition. Toxic effects may result from skin absorption. Bare unprotected skin should not be exposed to this material. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.
» The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.
» Prolonged or continuous skin contact with the liquid may cause defatting with drying, cracking, irritation and dermatitis following. Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS]. As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice.
» Not available. Refer to individual constituents. XYLENE: » unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
| TOXICITY | IRRITATION |
| Oral (human) LDLo: 50 mg/kg | Skin (rabbit):500 mg/24h Moderate |
| Oral (rat) LD50: 4300 mg/kg | Eye (human): 200 ppm Irritant |
| Inhalation (human) TCLo: 200 ppm | Eye (rabbit): 87 mg Mild |
| Inhalation (man) LCLo: 10000 ppm/6h | Eye (rabbit): 5 mg/24h SEVERE |
| Inhalation (rat) LC50: 5000 ppm/4h | |
| Oral (Human) LD: 50 mg/kg | |
| Inhalation (Human) TCLo: 200 ppm/4h | |
| Intraperitoneal (Rat) LD50: 2459 mg/kg | |
| Subcutaneous (Rat) LD50: 1700 mg/kg | |
| Oral (Mouse) LD50: 2119 mg/kg | |
| Intraperitoneal (Mouse) LD50: 1548 mg/kg | |
| Intravenous (Rabbit) LD: 129 mg/kg | |
| Inhalation (Guinea) pig: LC 450 ppm/4h |
| xylene | International Agency for Research on Cancer (IARC) Carcinogens | Group | 3 |
| xylene | ILO Chemicals in the electronics industry that have toxic effects on reproduction | Reduced fertility or sterility |
» DO NOT discharge into sewer or waterways. » WGK: Classification in accordance with German Water Resources Act. Water hazard class 2 (self-assessment): hazardous to water. Refer to data for ingredients, which follows: XYLENE: » Fish LC50 (96hr.) (mg/l): 13.5 » BCF<100: 2.14- 2.20 » log Kow (Prager 1995): 3.12- 3.20 » Half- life Soil - High (hours): 672 » Half- life Soil - Low (hours): 168 » Half- life Air - High (hours): 44 » Half- life Air - Low (hours): 2.6 » Half- life Surface water - High (hours): 672 » Half- life Surface water - Low (hours): 168 » Half- life Ground water - High (hours): 8640 » Half- life Ground water - Low (hours): 336 » Aqueous biodegradation - Aerobic - High (hours): 672 » Aqueous biodegradation - Aerobic - Low (hours): 168 » Aqueous biodegradation - Anaerobic - High (hours): 8640 » Aqueous biodegradation - Anaerobic - Low (hours): 4320 » Photolysis maximum light absorption - High (nano- m): 269.5 » Photolysis maximum light absorption - Low (nano- m): 265 » Photooxidation half- life water - High (hours): 2.70E+08 » Photooxidation half- life water - Low (hours): 3.90E+05 » Photooxidation half- life air - High (hours): 44 » Photooxidation half- life air - Low (hours): 2.6 » Harmful to aquatic organisms. » For xylenes : Environmental Fate Terrestrial fate:: Measured Koc values of 166 and 182, indicate that 3-xylene is expected to have moderate mobility in soil. Volatilisation of p-xylene is expected to be important from moist soil surfaces given a measured Henry's Law constant of 7.18x10-3 atm-cu m/mole. The potential for volatilisation of 3-xylene from dry soil surfaces may exist based on a measured vapor pressure of 8.29 mm Hg. p-Xylene may be degraded during its passage through soil). The extent of the degradation is expected to depend on its concentration, residence time in the soil, the nature of the soil, and whether resident microbial populations have been acclimated. p-Xylene, present in soil samples contaminated with jet fuel, was completely degraded aerobically within 5 days. In aquifer studies under anaerobic conditions, p-xylene was degraded, usually within several weeks, with the production of 3-methylbenzylfumaric acid, 3-methylbenzylsuccinic acid, 3-methylbenzoate, and 3-methylbenzaldehyde as metabolites. Aquatic fate: Koc values indicate that p-xylene may adsorb to suspended solids and sediment in water. p-Xylene is expected to volatilise from water surfaces based on the measured Henry's Law constant. Estimated volatilisation half-lives for a model river and model lake are 3 hours and 4 days, respectively. BCF values of 14.8, 23.4, and 6, measured in goldfish, eels, and clams, respectively, indicate that bioconcentration in aquatic organisms is low. p-Xylene in water with added humic substances was 50% degraded following 3 hours irradiation suggesting that indirect photooxidation in the presence of humic acids may play an important role in the abiotic degradation of p-xylene. Although p-xylene is biodegradable and has been observed to degrade in pond water, there are insufficient data to assess the rate of this process in surface waters. p-Xylene has been observed to degrade in anaerobic and aerobic groundwater in several studies; however, it is known to persist for many years in groundwater, at least at sites where the concentration might have been quite high. Atmospheric fate: Most xylenes released to the environment will occur in the atmosphere and volatilisation is the dominant environmental fate process. In the ambient atmosphere, xylenes are expected to exist solely in the vapour phase. Xylenes are degraded in the atmosphere primarily by reaction with photochemically-produced hydroxyl radicals, with an estimated atmospheric lifetime of about 0.5 to 2 days. Xylenes' susceptibility to photochemical oxidation in the troposphere is to the extent that they may contribute to photochemical smog formation. According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere and from its vapour pressure, p-xylene, is expected to exist solely as a vapour in the ambient atmosphere. Vapour-phase p-xylene is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals; the half-life for this reaction in air is estimated to be about 16 hours. A half-life of 1.0 hr in summer and 10 hr in winter was measured for the reaction of p-xylene with photochemically-produced hydroxyl radicals. p-Xylene has a moderately high photochemical reactivity under smog conditions, higher than the other xylene isomers, with loss rates varying from 9-42% per hr. The photooxidation of p-xylene results in the production of carbon monoxide, formaldehyde, glyoxal, methylglyoxal, 3-methylbenzylnitrate, m-tolualdehyde, 4-nitro-3-xylene, 5-nitro-3-xylene, 2,6-dimethyl-p-benzoquinone, 2,4-dimethylphenol, 6-nitro-2,4-dimethylphenol, 2,6-dimethylphenol, and 4-nitro-2,6-dimethylphenol. Ecotoxicity: for xylenes Fish LC50 (96 h) Pimephales promelas 13.4 mg/l; Oncorhyncus mykiss 8.05 mg/l; Lepomis macrochirus 16.1 mg/l (all flow through values); Pimephales promelas 26.7 (static) Daphnia EC50 948 h): 3.83 mg/l Photobacterium phosphoreum EC50 (24 h): 0.0084 mg/l Gammarus lacustris LC50 (48 h): 0.6 mg/l. DISTILLATES, PETROLEUM, LIGHT, HYDROTREATED: Marine Pollutant: Not Determined » For hydrocarbons: Environmental fate: The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of waters after release in calm sea conditions. This is expected to evaporate and enter the atmosphere where it will be degraded through reaction with hydroxy radicals. Some hydrocarbon will become associated with benthic sediments, and it is likely to be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or anaerobic. The material, in probability, is biodegradable, under aerobic conditions (isomerised olefins and alkenes show variable results). Evidence also suggests that the hydrocarbons may be degradable under anaerobic conditions although such degradation in benthic sediments may be a relatively slow process. Under aerobic conditions hydrocarbons degrade to water and carbon dioxide, while under anaerobic processes they produce water, methane and carbon dioxide. Alkenes have low log octanol/water partition coefficients (Kow) of about 1 and estimated bioconcentration factors (BCF) of about 10; aromatics have intermediate values (log Kow values of 2-3 and BCF values of 20-200), while C5 and greater alkanes have fairly high values (log Kow values of about 3-4.5 and BCF values of 100-1,500 The estimated volatilisation half-lives for alkanes and benzene, toluene, ethylbenzene, xylene (BTEX) components were predicted as 7 days in ponds, 1.5 days in rivers, and 6 days in lakes. The volatilisation rate of naphthalene and its substituted derivatives were estimated to be slower Indigenous microbes found in many natural settings (e.g., soils, groundwater, ponds) have been shown to be capable of degrading organic compounds. Unlike other fate processes that disperse contaminants in the environment, biodegradation can eliminate the contaminants without transferring them across media. The final products of microbial degradation are carbon dioxide, water, and microbial biomass. The rate of hydrocarbon degradation depends on the chemical composition of the product released to the environment as well as site-specific environmental factors. Generally the straight chain hydrocarbons and the aromatics are degraded more readily than the highly branched aliphatic compounds. The n-alkanes, n-alkyl aromatics, and the aromatics in the C10-C22 range are the most readily biodegradable; n-alkanes, n-alkyl aromatics, and aromatics in the C5-C9 range are biodegradable at low concentrations by some microorganisms, but are generally preferentially removed by volatilisation and thus are unavailable in most environments; n-alkanes in the C1-C4 ranges are biodegradable only by a narrow range of specialised hydrocarbon degraders; and n-alkanes, n-alkyl aromatics, and aromatics above C22 are generally not available to degrading microorganisms. Hydrocarbons with condensed ring structures, such as PAHs with four or more rings, have been shown to be relatively resistant to biodegradation. PAHs with only 2 or 3 rings (e.g., naphthalene, anthracene) are more easily biodegraded. In almost all cases, the presence of oxygen is essential for effective biodegradation of oil. The ideal pH range to promote biodegradation is close to neutral (6-8). For most species, the optimal pH is slightly alkaline, that is, greater than 7. All biological transformations are affected by temperature. Generally, as the temperature increases, biological activity tends to increase up to a temperature where enzyme denaturation occurs. Atmospheric fate: Alkanes, isoalkanes, and cycloalkanes have half-lives on the order of 1-10 days, whereas alkenes, cycloalkenes, and substituted benzenes have half-lives of 1 day or less. Photochemical oxidation products include aldehydes, hydroxy compounds, nitro compounds, and peroxyacyl nitrates. Alkenes, certain substituted aromatics, and naphthalene are potentially susceptible to direct photolysis. Ecotoxicity: Based on test results, as well as theoretical considerations, the potential for bioaccumulation may be high. Toxic effects are often observed in species such as blue mussel, daphnia, freshwater green algae, marine copepods and amphipods. The values of log Kow for individual hydrocarbons increase with increasing carbon number within homologous series of generic types. Quantitative structure activity relationships (QSAR), relating log Kow values of single hydrocarbons to toxicity, show that water solubility decreases more rapidly with increasing Kow than does the concentration causing effects. This relationship varies somewhat with species of hydrocarbon, but it follows that there is a log Kow limit for hydrocarbons, above which, they will not exhibit acute toxicity; this limit is at a log Kow value of about 4 to 5. It has been confirmed experimentally that for fish and invertebrates, paraffinic hydrocarbons with a carbon number of 10 or higher (log Kow >5) show no acute toxicity and that alkylbenzenes with a carbon number of 14 or greater (log Kow >5) similarly show no acute toxicity. QSAR equations for chronic toxicity also suggest that there should be a point where hydrocarbons with high log Kow values become so insoluble in water that they will not cause chronic toxicity, that is, that there is also a solubility cut-off for chronic toxicity. Thus, paraffinic hydrocarbons with carbon numbers of greater than 14 (log Kow >7.3) should show no measurable chronic toxicity. » Drinking Water Standards: hydrocarbon total: 10 ug/l (UK max.).
· Recycle wherever possible or consult manufacturer for recycling options.
· Consult State Land Waste Management Authority for disposal.
· Bury residue in an authorised landfill.
· Recycle containers if possible, or dispose of in an authorised landfill.
HAZCHEM: None (ADG7) NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG
Regulations for ingredients
0890 100 31 - Wurth Adhesive & Sealing Compound Black (CAS: None):
No regulations applicable
xylene (CAS: 1330-20-7) is found on the following regulatory lists;
Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - organic compounds)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Domestic water quality
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix I
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
GESAMP/EHS Composite List of Hazard Profiles - Hazard evaluation of substances transported by ships
IMO IBC Code Chapter 17: Summary of minimum requirements
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
IMO Provisional Categorization of Liquid Substances - List 1: Pure or technically pure products
International Agency for Research on Cancer (IARC) Carcinogens
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water
distillates, petroleum, light, hydrotreated (CAS: 64742-47-8) is found on the following regulatory lists;
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
calcium oxide (CAS: 1305-78-8) is found on the following regulatory lists;
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP
International Air Transport Association (IATA) Dangerous Goods Regulations
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
Substance CAS Suggested codes bis(1, 2, 2, 6, 6- pentamethyl- 4- 41556- 26- N; R51/53 piperidyl)sebacate 7 butyl benzyl phthalate 85- 68- 7 N; R50/53
Ingredient Name CAS calcium hydroxide 1305- 62- 0, 1332- 69- 0
Ingredient ORG UF Endpoint CR Adeq
TLV
xylene 1.5 mg/m3 10 D NA -
» These exposure guidelines have been derived from a screening level of risk assessment and should not be
construed as unequivocally safe limits. ORGS represent an 8-hour time-weighted average unless specified
otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
» "Worst Case" computer-aided prediction of vapour components/concentrations: » Composite Exposure Standard for Mixture (TWA) (mg/m3): 2100 mg/m³ » If the breathing zone concentration of ANY of the components listed below is exceeded, "Worst Case" considerations deem the individual to be overexposed. Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
| Component | Breathing zone (ppm) | Breathing zone (mg/m3) | Mixture Conc (%) |
| distillates, petroleum, light, hydrotreated | 300.00 | 2100.0000 | 5.0 |
» Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
» The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 24-Mar-2009
Print Date: 24-Mar-2009
This is the end of the MSDS.