0890 100 6 - WURTH KD BOND & SEAL SANDSTONE
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Feb-2010
NC317ECP
CHEMWATCH 4725-28
Version No:5
0890 100 6 - WURTH KD BOND & SEAL SANDSTONE
"Manufacturer's Code 0890 100 6"
Adhesive / sealant.
Company: Wurth Pty Ltd
Address:
4 Redwood Drive (abn 48 002 487 096)
Dingley
VIC, 3172
AUS
Telephone: +61 3 9552 9552
Telephone: 1800 331 603
Emergency Tel: 1300 657 765
Fax: +61 3 9551 2994
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
None
| RISK | SAFETY |
| ■ May cause SENSITISATION by inhalation. | ■ Wear suitable protective clothing. |
| ■ Harmful to aquatic organisms may cause long-term adverse effects in the aquatic environment. | ■ To clean the floor and all objects contaminated by this material use water and detergent. |
| ■ Keep away from food drink and animal feeding stuffs. | |
| ■ If swallowed IMMEDIATELY contact Doctor or Poisons Information Centre (show this container or label). |
| NAME | CAS RN | % |
| xylene | 1330-20-7 | 1-2.5 |
| naphtha, petroleum, hydrodesulfurised heavy | 64742-82-1. | 1-2.5^ |
| 4, 4' - diphenylmethane diisocyanate (MDI) | 101-68-8 | 0.1-<1^ |
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
· Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
· Seek medical advice.
· Avoid giving milk or oils.
· Avoid giving alcohol.
■ If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Seek medical attention without delay; if pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
■ If skin or hair contact occurs:
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
· Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
· Transport to hospital, or doctor.
■ For acute or short term repeated exposures to xylene: · Gastro-intestinal absorption is significant with ingestions. For ingestions exceeding 1-2 ml (xylene)/kg, intubation and lavage with cuffed endotracheal tube is recommended. The use of charcoal and cathartics is equivocal. · Pulmonary absorption is rapid with about 60-65% retained at rest. · Primary threat to life from ingestion and/or inhalation, is respiratory failure. · Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 < 50 mm Hg or pCO2 > 50 mm Hg) should be intubated. · Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves clearance. · A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of pneumothorax. · Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation to catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a second choice. BIOLOGICAL EXPOSURE INDEX - BEI These represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV):
| Determinant | Index | Sampling Time | Comments |
| Methylhippu-ric acids in urine | 1.5 gm/gm creatinine | End of shift | |
| 2 mg/min | Last 4 hrs of shift |
· There is no restriction on the type of extinguisher which may be used. · Use extinguishing media suitable for surrounding area.
· Alert Fire Brigade and tell them location and nature of hazard. · Wear breathing apparatus plus protective gloves for fire only. · Prevent, by any means available, spillage from entering drains or water courses. · Use fire fighting procedures suitable for surrounding area. · DO NOT approach containers suspected to be hot. · Cool fire exposed containers with water spray from a protected location. · If safe to do so, remove containers from path of fire. · Equipment should be thoroughly decontaminated after use.
· Non combustible. · Not considered a significant fire risk, however containers may burn.
· Avoid reaction with oxidising agents.
None
Gas tight chemical resistant suit.
· Clean up all spills immediately. · Avoid contact with skin and eyes. · Wear impervious gloves and safety goggles. · Trowel up/scrape up. · Place spilled material in clean, dry, sealed container. · Flush spill area with water.
· Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. · Stop leak if safe to do so. · Contain spill with sand, earth or vermiculite. · Collect recoverable product into labelled containers for recycling. · Neutralise/decontaminate residue. · Collect solid residues and seal in labelled drums for disposal. · Wash area and prevent runoff into drains. · After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. · If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Electrostatic discharge may be generated during pumping - this may result in fire.
· Ensure electrical continuity by bonding and grounding (earthing) all equipment.
· Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe submerged to twice its diameter, then <= 7 m/sec).
· Avoid splash filling.
· Do NOT use compressed air for filling discharging or handling operations.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· DO NOT enter confined spaces until atmosphere has been checked.
· DO NOT allow material to contact humans, exposed food or food utensils.
· Avoid contact with incompatible materials.
· When handling, DO NOT eat, drink or smoke.
· Keep containers securely sealed when not in use.
· Avoid physical damage to containers.
· Always wash hands with soap and water after handling.
· Work clothes should be laundered separately. Launder contaminated clothing before re-use.
· Use good occupational work practice.
· Observe manufacturer's storing and handling recommendations.
· Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.
· Polyethylene or polypropylene container.
· Packing as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.
· NOTE: May develop pressure in containers; open carefully. Vent periodically.
· Avoid reaction with oxidising agents.
· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.
| Source | Material | TWA ppm | TWA mg/m³ | STEL ppm | STEL mg/m³ | Notes |
| ___________ | ___________ | _______ | _______ | _______ | _______ | _______ |
| Australia Exposure Standards | xylene (Xylene (o-, m-, p- isomers)) | 80 | 350 | 150 | 655 | |
| Australia Exposure Standards | naphtha, petroleum, hydrodesulfurised heavy (White spirits) | 790 | (see Chapter 16) |
| Material | Revised IDLH Value (mg/m3) | Revised IDLH Value (ppm) |
| xylene | 900 |
0890 100 6 - WURTH KD BOND & SEAL SANDSTONE: Not available XYLENE: ■ for xylenes: IDLH Level: 900 ppm Odour Threshold Value: 20 ppm (detection), 40 ppm (recognition) NOTE: Detector tubes for o-xylene, measuring in excess of 10 ppm, are available commercially. (m-xylene and p-xylene give almost the same response). Xylene vapour is an irritant to the eyes, mucous membranes and skin and causes narcosis at high concentrations. Exposure to doses sufficiently high to produce intoxication and unconsciousness also produces transient liver and kidney toxicity. Neurologic impairment is NOT evident amongst volunteers inhaling up to 400 ppm though complaints of ocular and upper respiratory tract irritation occur at 200 ppm for 3 to 5 minutes. Exposure to xylene at or below the recommended TLV-TWA and STEL is thought to minimise the risk of irritant effects and to produce neither significant narcosis or chronic injury. An earlier skin notation was deleted because percutaneous absorption is gradual and protracted and does not substantially contribute to the dose received by inhalation. Odour Safety Factor(OSF) OSF=4 (XYLENE). Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed through intact skin. Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure and may also invalidate the exposure standard.
· Safety glasses with side shields · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
· Wear chemical protective gloves, eg. PVC. · Wear safety footwear or safety gumboots, eg. Rubber.
· Overalls. · P.V.C. apron. · Barrier cream. · Skin cleansing cream. · Eye wash unit.
■ Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important.
| Breathing Zone Level ppm (volume) | Maximum Protection Factor | Half-face Respirator | Full-Face Respirator |
| 1000 | 10 | A-AUS | - |
| 1000 | 50 | - | A-AUS |
| 5000 | 50 | Airline * | - |
| 5000 | 100 | - | A-2 |
| 10000 | 100 | - | A-3 |
| 100+ | Airline** |
■ Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection. Supplied-air type respirator may be required in special circumstances. Correct fit is essential to ensure adequate protection. An approved self contained breathing apparatus (SCBA) may be required in some situations. Provide adequate ventilation in warehouse or closed storage area.
Paste with a characteristic odour; reacts with water forming carbon dioxide.
| State | Non Slump Paste | Molecular Weight | Not Applicable |
| Melting Range (ºC) | Not Available | Viscosity | Not Available |
| Boiling Range (ºC) | Not Available | Solubility in water (g/L) | Reacts |
| Flash Point (ºC) | >70 (CC) | pH (1% solution) | Not Available |
| Decomposition Temp (ºC) | Not Available | pH (as supplied) | Not Applicable |
| Autoignition Temp (ºC) | Not Available | Vapour Pressure (kPa) | Not Available |
| Upper Explosive Limit (%) | Not Available | Specific Gravity (water=1) | ~1.26 |
| Lower Explosive Limit (%) | Not Available | Relative Vapour Density (air=1) | Not Available |
| Volatile Component (%vol) | Not Available | Evaporation Rate | Not Available |
■ Product is considered stable and hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
■ Considered an unlikely route of entry in commercial/industrial environments. Ingestion may result in nausea, abdominal irritation, pain and vomiting.
■ Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with windburn).
■ The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Open cuts, abraded or irritated skin should not be exposed to this material.
■ Inhalation hazard is increased at higher temperatures. Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination.
■ Inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population. Sensitisation may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitised persons should not be allowed to work in situations where exposure may occur. Sensitisation reactions may appear suddenly after repeatedsymptom free exposures. As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice.
■ Not available. Refer to individual constituents. XYLENE: ■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
| TOXICITY | IRRITATION |
| Oral (human) LDLo: 50 mg/kg | Skin (rabbit):500 mg/24h Moderate |
| Oral (rat) LD50: 4300 mg/kg | Eye (human): 200 ppm Irritant |
| Inhalation (human) TCLo: 200 ppm | Eye (rabbit): 87 mg Mild |
| Inhalation (man) LCLo: 10000 ppm/6h | Eye (rabbit): 5 mg/24h SEVERE |
| Inhalation (rat) LC50: 5000 ppm/4h | |
| Oral (Human) LD: 50 mg/kg | |
| Inhalation (Human) TCLo: 200 ppm/4h | |
| Intraperitoneal (Rat) LD50: 2459 mg/kg | |
| Subcutaneous (Rat) LD50: 1700 mg/kg | |
| Oral (Mouse) LD50: 2119 mg/kg | |
| Intraperitoneal (Mouse) LD50: 1548 mg/kg | |
| Intravenous (Rabbit) LD: 129 mg/kg | |
| Inhalation (Guinea) pig: LC 450 ppm/4h |
| Xylenes | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 3 |
| xylene | ILO Chemicals in the electronics industry that have toxic effects on reproduction | Reduced fertility or sterility |
Refer to data for ingredients, which follows: XYLENE: 0890 100 6 - WURTH KD BOND & SEAL SANDSTONE: ■ DO NOT discharge into sewer or waterways. ■ Harmful to aquatic organisms. 0890 100 6 - WURTH KD BOND & SEAL SANDSTONE: /53#90wgk Water hazard class 1 (self-assessment): slightly hazardous to water. [Wurth] XYLENE: ■ Fish LC50 (96hr.) (mg/l): 13.5 ■ BCF<100: 2.14- 2.20 ■ log Kow (Prager 1995): 3.12- 3.20 ■ Half- life Soil - High (hours): 672 ■ Half- life Soil - Low (hours): 168 ■ Half- life Air - High (hours): 44 ■ Half- life Air - Low (hours): 2.6 ■ Half- life Surface water - High (hours): 672 ■ Half- life Surface water - Low (hours): 168 ■ Half- life Ground water - High (hours): 8640 ■ Half- life Ground water - Low (hours): 336 ■ Aqueous biodegradation - Aerobic - High (hours): 672 ■ Aqueous biodegradation - Aerobic - Low (hours): 168 ■ Aqueous biodegradation - Anaerobic - High (hours): 8640 ■ Aqueous biodegradation - Anaerobic - Low (hours): 4320 ■ Photolysis maximum light absorption - High (nano- m): 269.5 ■ Photolysis maximum light absorption - Low (nano- m): 265 ■ Photooxidation half- life water - High (hours): 2.70E+08 ■ Photooxidation half- life water - Low (hours): 3.90E+05 ■ Photooxidation half- life air - High (hours): 44 ■ Photooxidation half- life air - Low (hours): 2.6 ■ For xylenes : log Koc : 2.05-3.08 Koc : 25.4-204 Half-life (hr) air : 0.24-42 Half-life (hr) H2O surface water : 24-672 Half-life (hr) H2O ground : 336-8640 Half-life (hr) soil : 52-672 Henry's Pa m3 /mol: 637-879 Henry's atm m3 /mol: 7.68E-03 BOD 5 if unstated: 1.4,1% COD : 2.56,13% ThOD : 3.125 BCF : 23 log BCF : 1.17-2.41 Environmental Fate Terrestrial fate:: Measured Koc values of 166 and 182, indicate that 3-xylene is expected to have moderate mobility in soil. Volatilisation of p-xylene is expected to be important from moist soil surfaces given a measured Henry's Law constant of 7.18x10-3 atm-cu m/mole. The potential for volatilisation of 3-xylene from dry soil surfaces may exist based on a measured vapor pressure of 8.29 mm Hg. p-Xylene may be degraded during its passage through soil). The extent of the degradation is expected to depend on its concentration, residence time in the soil, the nature of the soil, and whether resident microbial populations have been acclimated. p-Xylene, present in soil samples contaminated with jet fuel, was completely degraded aerobically within 5 days. In aquifer studies under anaerobic conditions, p-xylene was degraded, usually within several weeks, with the production of 3-methylbenzylfumaric acid, 3-methylbenzylsuccinic acid, 3-methylbenzoate, and 3-methylbenzaldehyde as metabolites. Aquatic fate: Koc values indicate that p-xylene may adsorb to suspended solids and sediment in water. p-Xylene is expected to volatilise from water surfaces based on the measured Henry's Law constant. Estimated volatilisation half-lives for a model river and model lake are 3 hours and 4 days, respectively. BCF values of 14.8, 23.4, and 6, measured in goldfish, eels, and clams, respectively, indicate that bioconcentration in aquatic organisms is low. p-Xylene in water with added humic substances was 50% degraded following 3 hours irradiation suggesting that indirect photooxidation in the presence of humic acids may play an important role in the abiotic degradation of p-xylene. Although p-xylene is biodegradable and has been observed to degrade in pond water, there are insufficient data to assess the rate of this process in surface waters. p-Xylene has been observed to degrade in anaerobic and aerobic groundwater in several studies; however, it is known to persist for many years in groundwater, at least at sites where the concentration might have been quite high. Atmospheric fate: Most xylenes released to the environment will occur in the atmosphere and volatilisation is the dominant environmental fate process. In the ambient atmosphere, xylenes are expected to exist solely in the vapour phase. Xylenes are degraded in the atmosphere primarily by reaction with photochemically-produced hydroxyl radicals, with an estimated atmospheric lifetime of about 0.5 to 2 days. Xylenes' susceptibility to photochemical oxidation in the troposphere is to the extent that they may contribute to photochemical smog formation. According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere and from its vapour pressure, p-xylene, is expected to exist solely as a vapour in the ambient atmosphere. Vapour-phase p-xylene is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals; the half-life for this reaction in air is estimated to be about 16 hours. A half-life of 1.0 hr in summer and 10 hr in winter was measured for the reaction of p-xylene with photochemically-produced hydroxyl radicals. p-Xylene has a moderately high photochemical reactivity under smog conditions, higher than the other xylene isomers, with loss rates varying from 9-42% per hr. The photooxidation of p-xylene results in the production of carbon monoxide, formaldehyde, glyoxal, methylglyoxal, 3-methylbenzylnitrate, m-tolualdehyde, 4-nitro-3-xylene, 5-nitro-3-xylene, 2,6-dimethyl-p-benzoquinone, 2,4-dimethylphenol, 6-nitro-2,4-dimethylphenol, 2,6-dimethylphenol, and 4-nitro-2,6-dimethylphenol. Ecotoxicity: for xylenes Fish LC50 (96 h) Pimephales promelas 13.4 mg/l; Oncorhyncus mykiss 8.05 mg/l; Lepomis macrochirus 16.1 mg/l (all flow through values); Pimephales promelas 26.7 (static) Daphnia EC50 948 h): 3.83 mg/l Photobacterium phosphoreum EC50 (24 h): 0.0084 mg/l Gammarus lacustris LC50 (48 h): 0.6 mg/l.
| Ingredient | Persistence: Water/Soil | Persistence: Air | Bioaccumulation | Mobility |
| xylene | LOW | LOW | LOW |
· Recycle wherever possible or consult manufacturer for recycling options.
· Consult State Land Waste Management Authority for disposal.
· Bury residue in an authorised landfill.
· Recycle containers if possible, or dispose of in an authorised landfill.
None (ADG7) NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG
None
Regulations for ingredients
"Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"
| Ingredient Name | CAS |
| naphtha, petroleum, hydrodesulfurised heavy | 64742-82-1, 64741-92-0, 8052-41-3, 1030262-12-4, 8032-32-4, 8030-30-6, 64742-88-7, 64742-89-8, 8002-05-9, 61789-95-5, 64742-48-9, 101795-02-2, 8031-06-9, 8030-31-7, 50813-73-5, 54847-97-1, 121448-83-7, 8031-38-7, 8031-39-8 |
| 4,4'-diphenylmethane diisocyanate (MDI) | 101-68-8, 26447-40-5 |
■ Established occupational exposure limits frequently do not take into consideration reproductive end points that are clearly below the thresholds for other toxic effects. Occupational reproductive guidelines (ORGs) have been suggested as an additional standard. These have been established after a literature search for reproductive no-observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level (LOAEL). In addition the US EPA's procedures for risk assessment for hazard identification and dose-response assessment as applied by NIOSH were used in the creation of such limits. Uncertainty factors (UFs) have also been incorporated.
| Ingredient | ORG | UF | Endpoint | CR | Adeq TLV |
| xylene | 1.5 mg/m3 | 10 | D | NA | - |
■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
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permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 9-Feb-2010
Print Date: 18-Feb-2010
This is the end of the MSDS.