0890 104 - WURTH BATTERY TERMINAL SPRAY
ChemWatch Material Safety Data Sheet
Issue Date: Mon 31-Jan-2005
CHEMWATCH 42208
0890 104 - WURTH BATTERY TERMINAL SPRAY
Manufacturer's Code 0890 104
AEROSOLS
Applied to battery posts to prevent corrosion. Application is by spray atomisation from a
hand held aerosol pack
Company: Wurth Australia Pty Ltd
Address:
4 Redwood Drive (abn 48 002 487 096)
Dingley
VIC, 3175
AUSTRALIA
Telephone: (+61 3) 9552 9552
Telephone: 1800 331 603
Emergency Tel: 1300 657 765
Fax: 03 9551 2994
HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
None
Extremely flammable.
Irritating to eyes and respiratory system.
Risk of explosion if heated under confinement.
Vapours may cause drowsiness and dizziness.
Do not breathe gas/fumes/vapour/spray.
Wear eye/face protection.
Use only in well ventilated areas.
Keep container in a well ventilated place.
Keep container tightly closed.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
if possible).
| NAME | CAS RN | % |
| methyl ethyl ketone | 78-93-3 | 1-20 |
| ethyl acetate | 141-78-6 | 1-20 |
| hydrocarbon propellant | 68476-85-7. | 20-80 |
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
· Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
· Seek medical advice.
If this product comes in contact with the eyes:
· Immediately hold eyelids apart and flush the eye continuously with running
water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Continue flushing until advised to stop by the Poisons Information Centre or a
doctor, or for at least 15 minutes.
· Transport to hospital or doctor without delay.
· Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
If solids or aerosol mists are deposited upon the skin:
· Flush skin and hair with running water (and soap if available).
· Remove any adhering solids with industrial skin cleansing cream.
· DO NOT use solvents.
· Seek medical attention in the event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
· Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
· Transport to hospital, or doctor.
Treat symptomatically.
· Water spray or fog.
· Foam.
· Dry chemical powder.
· BCF (where regulations permit).
· Carbon dioxide.
· Alert Fire Brigade and tell them location and nature of hazard.
· May be violently or explosively reactive.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water
course.
· If safe, switch off electrical equipment until vapour fire hazard removed.
· Use water delivered as a fine spray to control fire and cool adjacent area.
· DO NOT approach containers suspected to be hot.
· Cool fire exposed containers with water spray from a protected location.
· If safe to do so, remove containers from path of fire.
· Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.
· Liquid and vapour are highly flammable.
· Severe fire hazard when exposed to heat or flame.
· Vapour forms an explosive mixture with air.
· Severe explosion hazard, in the form of vapour, when exposed to flame or
spark.
· Vapour may travel a considerable distance to source of ignition.
· Heating may cause expansion or decomposition with violent container rupture.
· Aerosol cans may explode on exposure to naked flames.
· Rupturing containers may rocket and scatter burning materials.
· Hazards may not be restricted to pressure effects.
· May emit acrid, poisonous or corrosive fumes.
· On combustion, may emit toxic fumes of carbon monoxide (CO).
Avoid contamination with strong oxidising agents as ignition may result
2Y
PERSONAL PROTECTION EQUIPMENT
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set - 30 mins.
· Clean up all spills immediately.
· Avoid breathing vapours and contact with skin and eyes.
· Wear protective clothing, impervious gloves and safety glasses.
· Shut off all possible sources of ignition and increase ventilation.
· Wipe up.
· If safe, damaged cans should be placed in a container outdoors, away from all
ignition sources, until pressure has dissipated.
· Undamaged cans should be gathered and stowed safely.
· Clear area of personnel and move upwind.
· Alert Fire Brigade and tell them location and nature of hazard.
· May be violently or explosively reactive.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water
courses
· No smoking, naked lights or ignition sources.
· Increase ventilation.
· Stop leak if safe to do so.
· Water spray or fog may be used to disperse / absorb vapour.
· Absorb or cover spill with sand, earth, inert materials or vermiculite.
· If safe, damaged cans should be placed in a container outdoors, away from
ignition sources, until pressure has dissipated.
· Undamaged cans should be gathered and stowed safely.
· Collect residues and seal in labelled drums for disposal.
From IERG (Canada/Australia) Isolation Distance - Downwind Protection Distance 8 metres IERG Number 49
FOOTNOTES 1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on either side of the predominant wind direction, resulting in a crosswind protective action distance equal to the downwind protective action distance. 2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill and working away from the site in the downwind direction. Within the protective action zone a level of vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and unable to take protective action and/or incurring serious or irreversible health effects. 3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high probability of localised wind reversal may expose nearly all persons without appropriate protection to life-threatening concentrations of the material. 4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from a small cylinder are also considered "small spills". LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne" compressed gas cylinder. 5 Guide 126 is taken from the US DOT emergency response guide book. 6 IERG information is derived from CANUTEC - Transport Canada.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· DO NOT enter confined spaces until atmosphere has been checked.
· Avoid smoking, naked lights or ignition sources.
· Avoid contact with incompatible materials.
· When handling, DO NOT eat, drink or smoke.
· DO NOT incinerate or puncture aerosol cans.
· DO NOT spray directly on humans, exposed food or food utensils.
· Avoid physical damage to containers.
· Always wash hands with soap and water after handling.
· Work clothes should be laundered separately.
· Use good occupational work practice.
· Observe manufacturer's storing and handling recommendations.
· Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
DO NOT spray directly on humans, exposed food or food utensils.
· Aerosol dispenser.
· Check that containers are clearly labelled.
Avoid storage with oxidisers
· Store in original containers in approved flammable liquid storage area.
· DO NOT store in pits, depressions, basements or areas where vapours may be
trapped.
· No smoking, naked lights, heat or ignition sources.
· Keep containers securely sealed. Contents under pressure.
· Store away from incompatible materials.
· Store in a cool, dry, well ventilated area.
· Avoid storage at temperatures higher than 40 deg C.
· Store in an upright position.
· Protect containers against physical damage.
· Check regularly for spills and leaks.
· Observe manufacturer's storing and handling recommendations.
No data available for methyl ethyl ketone as (CAS: 78-93-3) / (CAS: 141-78-6) / (CAS: 68476-85-7) / (CAS: 68476-86-8)
None assigned. Refer to individual constituents.
OSF=0.16 (hydrocarbon propellant)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 As "A" for 50-90% of
persons being distracted
C 1-26 As "A" for less than 50%
of persons being
distracted
D 0.18-1 10-50% of persons aware
of being tested perceive
by smell that the
Exposure Standard is
being reached
E <0.18 As "D" for less than 10%
of persons aware of being
tested
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m³): 1277.512 mg/m³
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m³ Mixture Conc: (%)
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m³) (%)
ethyl acetate 255.5024 20.0
methyl ethyl ketone 86.12 255.5024 20.0
hydrocarbon propellant 425.84 766.5072 60.0
METHYL ETHYL KETONE:
TLV TWA: 200 ppm BEI [ACGIH]
TLV STEL: 300 ppm BEI [ACGIH]
PEL TWA: 200 ppm, 590 mg/m³ [OSHA Z1]
TLV TWA: 200 ppm, 590 mg/m³; STEL: 300 ppm, 885 mg/m³
ES TWA: 150 ppm, 445 mg/m³; STEL: 300 ppm, 890 mg/m³
OES TWA: 200 ppm, 600 mg/m³; STEL: 300 ppm, 899 mg/m³ skin
MAK value: 200 ppm, 600 mg/m³
Designated H in List of MAK values: Danger of cutaneous absorption.
Absorption of such substances through the skin can pose an incomparably larger
danger of toxicity than their inhalation. To avoid health risks when handling
such substances, meticulous cleaning of the skin, hair and clothing is
imperative.
MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
IDLH Level: 3000 ppm
Odour Threshold Value: Variously reported as 2 ppm and 4.8 ppm
Odour threshold: 2 ppm (detection); 5 ppm (recognition)
25 ppm (easy recognition); 300 ppm IRRITATING
Exposures at or below the recommended TLV-TWA are thought to prevent
injurious systemic effects and to minimise objections to odour and
irritation. Where synergism or potentiation may occur stringent control of
the primary toxin (e.g. n-hexane or methyl butyl ketone) is desirable and
additional consideration should be given to lowering MEK exposures.
ETHYL ACETATE:
TLV TWA: 400 ppm [ACGIH]
PEL TWA: 400 ppm, 1400 mg/m³ (SKIN) [OSHA Z1]
ES TWA: 200 ppm; STEL 400 ppm
TLV TWA: 400 ppm, 1440 mg/m³
OES TWA: 400 ppm, 1460 mg/m³
MAK value: 400 ppm, 1500 mg/m³
MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
IDLH Level: 2000 ppm (lower explosive limit)
Odour Threshold Value: 6.4-50 ppm (detection), 13.3-75 ppm (recognition)
The TLV-TWA provides a significant margin of safety from the standpoint of
adverse health effects. Unacclimated subjects found the odour
objectionably strong at 200 ppm. Mild nose, eye and throat irritation was
experienced at 400 ppm. Workers exposed regularly at concentrations
ranging from 375 ppm to 1500 ppm for several months showed no unusual
signs or symptoms.
HYDROCARBON PROPELLANT:
PEL TWA: 1000 ppm, 1800 mg/m³ [OSHA Z1]
hydrocarbon propellant, as liquified petroleum gas
TLV TWA: 1000 ppm, 1800 mg/m³
ES TWA: 1000 ppm, 1800 mg/m³
OES TWA: 1000 ppm, 1750 mg/m³; STEL: 1250 ppm, 2180 mg/m³
· Safety glasses with side shields; or as required, · Chemical goggles. · Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them.
· Barrier cream with polyethylene gloves. or. Wear chemical protective gloves, eg. PVC. Wear safety footwear.
· Overalls. · Eyewash unit.
Glove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: Substance ________________________________________ methyl ethyl ketone ethyl acetate PE/EVAL/PE A PVA A BUTYL B TEFLON B BUTYL/NEOPRENE B SARANEX-23 C NEOPRENE/NATURAL C HYPALON C NITRILE+PVC C PVC C NATURAL RUBBER C NEOPRENE C NATURAL+NEOPRENE C NITRILE C VITON/NEOPRENE C * CPI - Chemwatch Performance Index A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion C: Poor to Dangerous Choice for other than short term immersion NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. - * Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protection may be required when ANY "Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor Half-Face Respirator Full-Face Respirator
5 x ES Air-line* A-2
- A-PAPR-2
10 x ES - A-3
10+ x ES - Air-line**
* - Continuous Flow; ** - Continuous-flow or positive pressure demand
^ - Full-face
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
Use in a well-ventilated area. General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas.
Blue liquid with a characteristic odour; floats on water.
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
hydrocarbon propellant.
Liquid.
Does not mix with water.
Floats on water.
Molecular Weight: Not Applicable Boiling Range (ºC): Not Available Melting Range (ºC): Not Applicable Specific Gravity (water=1): 0.65 Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable pH (1% solution): Not Applicable Vapour Pressure (kPa): Under pressure Volatile Component (%vol): 90.1 Evaporation Rate: Not Available Relative Vapour Density (air=1): 0.65 Flash Point (ºC): -81 propellant Lower Explosive Limit (%): 1.3 Upper Explosive Limit (%): 11.5 Autoignition Temp (ºC): Not Available Decomposition Temp (ºC): Not Available State: Liquid
· Elevated temperatures.
· Presence of open flame.
· Product is considered stable.
· Hazardous polymerisation will not occur.
Overexposure is unlikely in this form.
Considered an unlikely route of entry in commercial/industrial environments.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by
aspiration may cause potentially lethal chemical pneumonitis.
The vapour when concentrated has pronounced eye irritation effects and this
gives some warning of high vapour concentrations. If eye irritation occurs seek
to reduce exposure with available control measures, or evacuate area.
The material may be irritating to the eye, with prolonged contact causing
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
Toxic effects may result from skin absorption.
The material may accentuate any pre-existing dermatitis condition.
The material may cause skin irritation after prolonged or repeated exposure and
may produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis.
Histologically there may be intercellular oedema of the spongy layer
(spongiosis) and intracellular oedema of the epidermis.
Inhalation hazard is increased at higher temperatures.
Acute effects from inhalation of high concentrations of vapour are pulmonary
irritation, including coughing, with nausea; central nervous system depression -
characterised by headache and dizziness, increased reaction time, fatigue and
loss of co-ordination.
If exposure to highly concentrated solvent atmosphere is prolonged this may lead
to narcosis, unconsciousness, even coma and possible death.
Inhalation of vapour may aggravate a pre-existing respiratory condition such as
asthma, bronchitis, emphysema.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Principal routes of exposure are by accidental skin and eye contact and by inhalation of
vapours especially at higher temperatures. Prolonged or continuous skin contact with the
liquid may cause defatting with drying, cracking, irritation and dermatitis following.
WARNING: Aerosol containers may present pressure related hazards.
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
METHYL ETHYL KETONE:
TOXICITY IRRITATION
Oral (rat) LD50: 2737 mg/kg Eye (human): 350 ppm -irritant
Inhalation (human) TCLo: 100 ppm/5 m Eye (rabbit): 80 mg - irritant
Inhalation (rat) LD50: 23500 mg/m3/8 hr Skin (rabbit): 402 mg/24 hr - mild
Dermal (rabbit) LD50: 6480 mg/kg Skin (rabbit):13.78mg/24 hr open
- mild
ETHYL ACETATE:
IRRITATIO TOXICITY
Eye (human): 400 ppm Oral (rat) LD50: 5620 mg/kg
Inhalation (rat) LC50: 1600 ppm/8h
Inhalation (human) TCLo: 400 ppm
HYDROCARBON PROPELLANT:
No significant acute toxicological data identified in literature search.
Water hazard class 1 (Self-assessment): slightly hazardous to water.
· Consult State Land Waste Management Authority for disposal.
· Discharge contents of damaged aerosol cans at an approved site.
· Allow small quantities to evaporate.
· DO NOT incinerate or puncture aerosol cans.
· Bury residues and emptied aerosol cans at an approved site.
Shipping Name:
AEROSOLS
Dangerous Goods Class: 2.1
UN/NA Number: 1950
ADR Number: None
Packing Group: None
Labels Required: flammable gas
Additional Shipping Information:
International Transport Regulations:
IMO: 2.1
2Y
None
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CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Mon 31-Jan-2005
Print Date: Wed 9-Feb-2005