0890 108 7 - WURTH BRAKE CLEANER CFC FREE
ChemWatch Material Safety Data Sheet
Issue Date: Mon 31-Jan-2005
CHEMWATCH 50610
0890 108 7 - WURTH BRAKE CLEANER CFC FREE
Manufacturer's Code 0890 108 7
AEROSOLS
Sprayed onto brakes to remove oil and grease.
Company: Wurth Australia Pty Ltd
Address:
4 Redwood Drive (abn 48 002 487 096)
Dingley
VIC, 3175
AUSTRALIA
Telephone: (+61 3) 9552 9552
Telephone: 1800 331 603
Emergency Tel: 1300 657 765
Fax: 03 9551 2994
HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
None
Extremely flammable.
Irritating to eyes.
Risk of explosion if heated under confinement.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Vapours may cause drowsiness and dizziness.
Keep container in a well ventilated place.
Avoid exposure - obtain special instructions before use.
To clean the floor and all objects contaminated by this material, use water and
detergent.
Keep container tightly closed.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (show
this container or label).
If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
if possible).
| NAME | CAS RN | % |
| naphtha petroleum, light, hydrotreated | 64742-49-0. | 30-80 |
| isopropanol | 67-63-0 | 20-40 |
| carbon dioxide | 124-38-9 | 1-10 |
For advice, contact a Poisons Information Centre or a doctor.
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconsciousness
· Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
· Seek medical advice.
If this product comes in contact with the eyes:
· Immediately hold eyelids apart and flush the eye continuously with running
water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Continue flushing until advised to stop by the Poisons Information Centre or a
doctor, or for at least 15 minutes.
· Transport to hospital or doctor without delay.
· Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
If solids or aerosol mists are deposited upon the skin:
· Flush skin and hair with running water (and soap if available).
· Remove any adhering solids with industrial skin cleansing cream.
· DO NOT use solvents.
· Seek medical attention in the event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
· Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
· Transport to hospital, or doctor.
For acute or short term repeated exposures to petroleum distillates or related hydrocarbons: · Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure. · Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated. · Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves clearance. · A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of pneumothorax. · Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation to catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a second choice. · Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology]
· Water spray or fog.
· Foam.
· Dry chemical powder.
· BCF (where regulations permit).
· Carbon dioxide.
· Alert Fire Brigade and tell them location and nature of hazard.
· May be violently or explosively reactive.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water
course.
· If safe, switch off electrical equipment until vapour fire hazard removed.
· Use water delivered as a fine spray to control fire and cool adjacent area.
· DO NOT approach containers suspected to be hot.
· Cool fire exposed containers with water spray from a protected location.
· If safe to do so, remove containers from path of fire.
· Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.
· Liquid and vapour are highly flammable.
· Severe fire hazard when exposed to heat or flame.
· Vapour forms an explosive mixture with air.
· Severe explosion hazard, in the form of vapour, when exposed to flame or
spark.
· Vapour may travel a considerable distance to source of ignition.
· Heating may cause expansion or decomposition with violent container rupture.
· Aerosol cans may explode on exposure to naked flames.
· Rupturing containers may rocket and scatter burning materials.
· Hazards may not be restricted to pressure effects.
· May emit acrid, poisonous or corrosive fumes.
· On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include carbon dioxide (CO2)
Avoid contamination with strong oxidising agents as ignition may result
2Y
PERSONAL PROTECTION EQUIPMENT
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set - 30 mins.
· Clean up all spills immediately.
· Avoid breathing vapours and contact with skin and eyes.
· Wear protective clothing, impervious gloves and safety glasses.
· Shut off all possible sources of ignition and increase ventilation.
· Wipe up.
· If safe, damaged cans should be placed in a container outdoors, away from all
ignition sources, until pressure has dissipated.
· Undamaged cans should be gathered and stowed safely.
· Clear area of personnel and move upwind.
· Alert Fire Brigade and tell them location and nature of hazard.
· May be violently or explosively reactive.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water
courses
· No smoking, naked lights or ignition sources.
· Increase ventilation.
· Stop leak if safe to do so.
· Water spray or fog may be used to disperse / absorb vapour.
· Absorb or cover spill with sand, earth, inert materials or vermiculite.
· If safe, damaged cans should be placed in a container outdoors, away from
ignition sources, until pressure has dissipated.
· Undamaged cans should be gathered and stowed safely.
· Collect residues and seal in labelled drums for disposal.
From IERG (Canada/Australia) Isolation Distance - Downwind Protection Distance 8 metres IERG Number 49
FOOTNOTES 1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on either side of the predominant wind direction, resulting in a crosswind protective action distance equal to the downwind protective action distance. 2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill and working away from the site in the downwind direction. Within the protective action zone a level of vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and unable to take protective action and/or incurring serious or irreversible health effects. 3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high probability of localised wind reversal may expose nearly all persons without appropriate protection to life-threatening concentrations of the material. 4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from a small cylinder are also considered "small spills". LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne" compressed gas cylinder. 5 Guide 126 is taken from the US DOT emergency response guide book. 6 IERG information is derived from CANUTEC - Transport Canada.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· DO NOT enter confined spaces until atmosphere has been checked.
· Avoid smoking, naked lights or ignition sources.
· Avoid contact with incompatible materials.
· When handling, DO NOT eat, drink or smoke.
· DO NOT incinerate or puncture aerosol cans.
· DO NOT spray directly on humans, exposed food or food utensils.
· Avoid physical damage to containers.
· Always wash hands with soap and water after handling.
· Work clothes should be laundered separately.
· Use good occupational work practice.
· Observe manufacturer's storing and handling recommendations.
· Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
· Aerosol dispenser.
· Check that containers are clearly labelled.
Avoid storage with oxidisers
· Store in original containers in approved flame-proof area.
· DO NOT store in pits, depressions, basements or areas where vapours may be
trapped.
· No smoking, naked lights, heat or ignition sources.
· Keep containers securely sealed. Contents under pressure.
· Store away from incompatible materials.
· Store in a cool, dry, well ventilated area in an upright position.
· Avoid storage at temperatures higher than 40 deg C.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.
No data available for naphtha petroleum, light, hydrotreated as (CAS: 64742-49-0) / (CAS: 67-63-0) / (CAS: 124-38-9)
None assigned. Refer to individual constituents.
OSF=0.068 (CARBON DIOXIDE)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 As "A" for 50-90% of
persons being distracted
C 1-26 As "A" for less than 50%
of persons being
distracted
D 0.18-1 10-50% of persons aware
of being tested perceive
by smell that the
Exposure Standard is
being reached
E <0.18 As "D" for less than 10%
of persons aware of being
tested
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m³): 3377.1107 mg/m³
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m³ Mixture Conc: (%)
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m³) (%)
isopropanol 1350.8443 40.0
naphtha petroleum, light, hydrotre 498.12 1992.4953 59.0
carbon dioxide 18.76 33.7711 1.0
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m³ (compare OSHA TWA)
ISOPROPANOL:
NOTICE OF INTENDED CHANGE
TLV TWA: 400 ppm [ACGIH]
TLV STEL: NOTICE OF INTENDED CHANGE 500 ppm [ACGIH]
TLV TWA: 200 ppm A4 [ACGIH]
TLV STEL: 400 ppm A4 [ACGIH]
PEL TWA: 400 ppm, 980 mg/m³ [OSHA Z1]
TLV TWA: 200 ppm; STEL: 400 ppm A4
NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as
causing Cancer in humans
ES TWA: 400 ppm, 980 mg/m³; STEL: 500 ppm, 1225 mg/m³ (Under review)
OES TWA: 400 ppm, 999 mg/m³; STEL: 500 ppm, 1250 mg/m³
MAK value: 200 ppm, 500 mg/m³
MAK Category II Peak Limitation: For substances with systemic effects and with a
half-life in humans of less than two hours.
Allows excursions of 2 times the MAK value, for 30 minutes (on average), four
times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
IDLH Level: 2000 ppm (lower explosive limit)
Odour Threshold Value: 3.3 ppm (detection), 7.6 ppm (recognition)
Exposure at or below the recommended TLV-TWA and STEL is thought to
minimise the potential for inducing narcotic effects or significant
irritation of the eyes or upper respiratory tract. It is believed, in the
absence of hard evidence, that this limit also provides protection against
the development of chronic health effects. The limit is intermediate to
that set for ethanol, which is less toxic, and n-propyl alcohol, which is
more toxic, than isopropanol.
CARBON DIOXIDE:
TLV TWA: 5000 ppm [ACGIH]
TLV STEL: 30000 ppm [ACGIH]
PEL TWA: 5000 ppm, 9000 mg/m³ [OSHA Z1]
carbon dioxide gas:
ES TWA: 5000 ppm, 9000 mg/m³; STEL: 30000 ppm, 54000 mg/m³
TLV TWA: 5000 ppm, 9000 mg/m³; STEL: 30000 ppm, 54000 mg/m³
OES TWA: 5000 ppm, 9150 mg/m³; STEL: 15000 ppm, 27400 mg/m³
MAK value: 5000 ppm, 9100 mg/m³
MAK Category IV Peak Limitation: For substances with very weak effects (ie.)
those with MAK value >500 ml/m³ (ppm): Allows excursions of twice the MAK value
for 60 minutes at a time, 3 times per shift.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
IDLH Level: 40000 ppm
NOTE: Detector tubes for carbon dioxide, measuring in excess of 0.01 % vol.,
are commercially available. Long-term measurements (4 hrs) may be
conducted to detect concentrations exceeding 250 ppm.
Studies using physically fit males in confined spaces indicate the TLV-TWA
and STEL provides a wide margin of safety against asphyxiation and from
undue metabolic stress, provided normal amounts of oxygen are present in
inhaled air. Lowered oxygen content, increased physical activity and
prolonged exposures each impact on systemic and respiratory effects.
Stimulation of the respiratory centre is produced at 50,000 ppm (5%). The
gas is weakly narcotic at 30,000 ppm giving rise to reduced acuity of
hearing and increasing blood pressure and pulse, Persons exposed at
20,000 ppm for several hours developed headaches and dyspnea on mild
exertion, Acidosis and adrenal cortical exhaustion occurred as a result
of prolonged continuous exposure at 10,000-20,0000 ppm.
Intoxication occurs after a 30 minute exposure at 50,000 ppm whilst
exposure at 70,000-100,000 ppm produces unconsciousness within a few
minutes.
· Safety glasses with side shields; or as required, · Chemical goggles. · Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them.
No special equipment needed when handling small quantities. OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves. Or as required: Wear chemical protective gloves, eg. PVC. Wear safety footwear.
No special equipment needed when handling small quantities. OTHERWISE: · Overalls. · Skin cleansing cream. · Eyewash unit. · Do not spray on hot surfaces.
Glove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: Substance ________________________________________ isopropanol NITRILE+PVC A PE/EVAL/PE A NITRILE A NEOPRENE A PVC B NAT+NEOPR+NITRILE C NATURAL RUBBER C NATURAL+NEOPRENE C * CPI - Chemwatch Performance Index A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion C: Poor to Dangerous Choice for other than short term immersion NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. - * Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protection may be required when ANY "Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor Half-Face Respirator Full-Face Respirator
5 x ES Air-line* A-2
- A-PAPR-2
10 x ES - A-3
10+ x ES - Air-line**
* - Continuous Flow; ** - Continuous-flow or positive pressure demand
^ - Full-face
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas.
Colourless liquid with solvent odour; does not mix with water. Supplied in
aerosol pack containing carbon dioxide propellant.
Liquid.
Does not mix with water.
Floats on water.
Molecular Weight: Not Applicable Boiling Range (ºC): 63 Melting Range (ºC): Not Available Specific Gravity (water=1): 0.71 Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable pH (1% solution): Not Applicable Vapour Pressure (kPa): 0.55 @ 20 degC. Volatile Component (%vol): 95 Evaporation Rate: Not Available Relative Vapour Density (air=1): 0.71 @ 20 degC. Flash Point (ºC): <21 Lower Explosive Limit (%): 0.8 Upper Explosive Limit (%): 12 Autoignition Temp (ºC): 250 Decomposition Temp (ºC): Not Available State: Liquid
· Elevated temperatures.
· Presence of open flame.
· Product is considered stable.
· Hazardous polymerisation will not occur.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by
aspiration may cause potentially lethal chemical pneumonitis.
Considered an unlikely route of entry in commercial/industrial environments
The material may produce severe irritation to the eye causing pronounced
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
Toxic effects may result from skin absorption.
The material may accentuate any pre-existing skin condition.
The material may cause skin irritation after prolonged or repeated exposure and
may produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling epidermis. Histologically
there may be intercellular oedema of the spongy layer (spongiosis) and
intracellular oedema of the epidermis.
Inhalation hazard is increased at higher temperatures.
Acute effects from inhalation of high concentrations of vapour are pulmonary
irritation, including coughing, with nausea; central nervous system depression -
characterised by headache and dizziness, increased reaction time, fatigue and
loss of co-ordination.
If exposure to highly concentrated solvent atmosphere is prolonged this may lead
to narcosis, unconsciousness, even coma and possible death.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Principal routes of exposure are by skin contact/absorption and inhalation of
mist/vapours. Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS]. Prolonged or continuous skin contact with the
liquid may cause defatting with drying, cracking, irritation and dermatitis following.
WARNING: Aerosol containers may present pressure related hazards.
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
No significant acute toxicological data identified in literature search.
ISOPROPANOL:
TOXICITY IRRITATION
Oral (human) LDLo: 3570 mg/kg Skin (rabbit): 500 mg - mild
Oral (human) TDLo: 223 mg/kg Eye (rabbit): 10 mg - moderate
Oral (man) TDLo: 14432 mg/kg Eye (rabbit): 100mg/24hr-moderate
Oral (rat) LD50: 5045 mg/kg Eye (rabbit): 100 mg - SEVERE
Dermal (rabbit) LD50: 12800 mg/kg
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
CARBON DIOXIDE:
TOXICITY IRRITATION
carbon dioxide gas:
Inhalation (human) LCLo:10 pph/ 1 m (10%) Nil reported
Inhalation (human) LCLo:9 pph/5 m (9%)
Inhalation (rat) LCLo: 657190 ppm/15 m
Inhalation (human) TCLo: 2000 ppm
- pulmonary effects
IDLH: 50,000 ppm
Refer to data for ingredients, which follows: NAPHTHA PETROLEUM, LIGHT, HYDROTREATED: No data for naphtha petroleum, light, hydrotreated. ISOPROPANOL: Hazardous Air Pollutant: No log Kow (Sangster 1997): 0.05 log Pow (Verschueren 1983): -0.5714285 BOD5: 60% BOD20: 78% COD: 2.23 ThOD: 2.4 Half-life Soil - High (hours): 168 Half-life Soil - Low (hours): 24 Half-life Air - High (hours): 72 Half-life Air - Low (hours): 6.2 Half-life Surface water - High (hours): 168 Half-life Surface water - Low (hours): 24 Half-life Ground water - High (hours): 336 Half-life Ground water - Low (hours): 48 Aqueous biodegradation - Aerobic - High (hours): 168 Aqueous biodegradation - Aerobic - Low (hours): 24 Aqueous biodegradation - Anaerobic - High (hours): 672 Aqueous biodegradation - Anaerobic - Low (hours): 96 Photooxidation half-life water - High (hours): 1.90E+05 Photooxidation half-life water - Low (hours): 4728 Photooxidation half-life air - High (hours): 72 Photooxidation half-life air - Low (hours): 6.2 log Kow : -0.16- 0.28 Half-life (hr) air : 33-84 Half-life (hr) H2O surface water : 130 Henry's atm m3 /mol: 8.07E-06 BOD 5 if unstated: 1.19,60% COD : 1.61-2.30,97% ThOD : 2.4 Aquatic toxicity (fish) 24-96h TLm: 42.5-240 mg/l (fish) 96h LC50: 4200-9640 mg/l * (daphnia) 48h EC50: 2285 mg/l * BOD 20: >70% * * [Akzo Nobel] CARBON DIOXIDE: Hazardous Air Pollutant: No log Kow (Sangster 1997): 0.83
· Consult State Land Waste Management Authority for disposal.
· Discharge contents of damaged aerosol cans at an approved site.
· Allow small quantities to evaporate.
· DO NOT incinerate or puncture aerosol cans.
· Bury residues and emptied aerosol cans at an approved site.
Shipping Name:
AEROSOLS
Dangerous Goods Class: 2.1
UN/NA Number: 1950
ADR Number: None
Packing Group: None
Labels Required: flammable gas
Additional Shipping Information:
International Transport Regulations:
IMO: 2.1
2Y
None
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CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Mon 31-Jan-2005
Print Date: Wed 9-Feb-2005