0890 108 93 - WURTH MULTI CLEAN NF - NON FLAMMABLE

Chemwatch Material Safety Data Sheet

Issue Date: 28-May-2008

NC317ECP

CHEMWATCH 15-6898

Version No:2.0

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

0890 108 93 - WURTH MULTI CLEAN NF - NON FLAMMABLE

PROPER SHIPPING NAME

AEROSOLS

PRODUCT USE

Application is by spray atomisation from a hand held aerosol pack. Cleaner.

SUPPLIER

Company: Wurth Pty Ltd                
Address:                              
4 Redwood Drive (abn 48 002 487 096)  
Dingley                               
VIC, 3172                             
AUS                                   
Telephone: +61 3 9552 9552            
Telephone: 1800 331 603               
Emergency Tel: 1300 657 765           
Fax: +61 3 9551 2994                  
                                      

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC,
and the ADG Code.

POISONS SCHEDULE

None

 

RISK SAFETY
Irritating to eyes and skin. Do not breathe gas/ fumes/ vapour/ spray.
Risk of explosion if heated under confinement. Avoid contact with skin.
Vapours may cause drowsiness and dizziness. Wear eye/ face protection.
To clean the floor and all objects contaminated by this material use water and detergent.
In case of contact with eyes rinse with plenty of water and contact Doctor or Poisons Information Centre.
If swallowed IMMEDIATELY contact Doctor or Poisons Information Centre (show this container or label).
This material and its container must be disposed of as hazardous waste.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
tetrachloroethylene 127-18-4 N/S
acetone 67-64-1 N/S^
carbon dioxide 124-38-9 N/S^

Section 4 - FIRST AID MEASURES

SWALLOWED

Not considered a normal route of entry.
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
· Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
· Seek medical advice.

EYE

If aerosols come in contact with the eyes:
· Immediately hold the eyelids apart and flush the eye continuously for at least 15
minutes with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
· Transport to hospital or doctor without delay.
· Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.

SKIN

If solids or aerosol mists are deposited upon the skin:
· Flush skin and hair with running water (and soap if available).
· Remove any adhering solids with industrial skin cleansing cream.
· DO NOT use solvents.
· Seek medical attention in the event of irritation.

INHALED

If aerosols, fumes or combustion products are inhaled:
· Remove to fresh air.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
· If breathing is shallow or has stopped, ensure clear airway and apply resuscitation,
preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as
trained. Perform CPR if necessary.
· Transport to hospital, or doctor.

NOTES TO PHYSICIAN

Treat symptomatically.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

SMALL FIRE:
· Water spray, dry chemical or CO2
LARGE FIRE:
· Water spray or fog.

FIRE FIGHTING

· Alert Fire Brigade and tell them location and nature of hazard.
· May be violently or explosively reactive.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water course.
· If safe, switch off electrical equipment until vapour fire hazard removed.
· Use water delivered as a fine spray to control fire and cool adjacent area.
· DO NOT approach containers suspected to be hot.
· Cool fire exposed containers with water spray from a protected location.
· If safe to do so, remove containers from path of fire.
· Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.

FIRE/EXPLOSION HAZARD

· Non combustible.
· Not considered to be a significant fire risk.
· Heating may cause expansion or decomposition leading to violent rupture of containers.
· Aerosol cans may explode on exposure to naked flames.
· Rupturing containers may rocket and scatter burning materials.
· Hazards may not be restricted to pressure effects.
· May emit acrid, poisonous or corrosive fumes.
· Decomposes on heating and may emit toxic fumes of carbon monoxide (CO).
Decomposition may produce toxic fumes of: carbon dioxide (CO2), hydrogen chloride,
phosgene, other pyrolysis products typical of burning organic material.

FIRE INCOMPATIBILITY

· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.

HAZCHEM: 2Y

Personal Protective Equipment

Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set 30 mins.

Section 6 - ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES

MINOR SPILLS

· Clean up all spills immediately.
· Avoid breathing vapours and contact with skin and eyes.
· Wear protective clothing, impervious gloves and safety glasses.
· Shut off all possible sources of ignition and increase ventilation.
· Wipe up.
· If safe, damaged cans should be placed in a container outdoors, away from all ignition 
sources, until pressure has dissipated.
· Undamaged cans should be gathered and stowed safely.

MAJOR SPILLS

· Clear area of personnel and move upwind.
· Alert Fire Brigade and tell them location and nature of hazard.
· May be violently or explosively reactive.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water courses
· No smoking, naked lights or ignition sources.
· Increase ventilation.
· Stop leak if safe to do so.
· Water spray or fog may be used to disperse / absorb vapour.
· Absorb or cover spill with sand, earth, inert materials or vermiculite.
· If safe, damaged cans should be placed in a container outdoors, away from ignition 
sources, until pressure has dissipated.
· Undamaged cans should be gathered and stowed safely.
· Collect residues and seal in labelled drums for disposal.

PROTECTIVE ACTIONS FOR SPILL

From IERG (Canada/Australia)
Isolation Distance            -
Downwind Protection Distance  8 metres
IERG Number                   49

 

FOOTNOTES
1  PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
    assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
    either side of the predominant wind direction, resulting in a crosswind protective action distance equal
    to the downwind protective action distance.
2  PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
    and working away from the site in the downwind direction. Within the protective action zone a level of
    vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
    unable to take protective action and/or incurring serious or irreversible health effects.
3  INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
    probability of localised wind reversal may expose nearly all persons without appropriate protection to
    life-threatening concentrations of the material.
4  SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
    box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
    a small cylinder are also considered "small spills".
   LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
    a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5  Guide 126 is taken from the US DOT emergency response guide book.
6  IERG information is derived from CANUTEC - Transport Canada.

 

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· DO NOT enter confined spaces until atmosphere has been checked.
· Avoid smoking, naked lights or ignition sources.
· Avoid contact with incompatible materials.
· When handling, DO NOT eat, drink or smoke.
· DO NOT incinerate or puncture aerosol cans.
· DO NOT spray directly on humans, exposed food or food utensils.
· Avoid physical damage to containers.
· Always wash hands with soap and water after handling.
· Work clothes should be laundered separately.
· Use good occupational work practice.
· Observe manufacturer's storing and handling recommendations.
· Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.

SUITABLE CONTAINER

· Aerosol dispenser.
· Check that containers are clearly labelled.

STORAGE INCOMPATIBILITY

· Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS

· Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and
internal pressure may eject contents of can.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

SourceMaterialTWA ppmTWA mg/m³STEL ppmSTEL mg/m³
________________________________________________________________
Australia Exposure Standardstetrachloroethylene (Perchloroethylene)503401501020
Australia Exposure Standardsacetone (Acetone)500118510002375
Australia Exposure Standardscarbon dioxide (Carbon dioxide in coal mines)12500225003000054000
Australia Exposure Standardscarbon dioxide (Carbon dioxide)500090003000054000

 

EMERGENCY EXPOSURE LIMITS

Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
tetrachloroethylene 150

 

MATERIAL DATA

Not available. Refer to individual constituents.

INGREDIENT DATA

TETRACHLOROETHYLENE:
Established occupational exposure limits frequently do not take into consideration 
reproductive end points that are clearly below the thresholds for other toxic effects. 
Occupational reproductive guidelines (ORGs) have been suggested as an additional 
standard. These have been established after a literature search for the reproductive no-
observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level 
(LOAEL). In addition the US EPA's procedures for risk assessment for hazard 
identification and dose-response assessment as applied by NIOSH were used in the creation 
of such limits. Uncertainty factors (UFs) have also been incorporated.
:.
These exposure guidelines have been derived from a screening level of risk assessment and 
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time-
weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure 
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:

Class OSF Description
A 550 Over 90% of exposed individuals are aware by smell that the Exposure Standard (TLV-TWA for example) is being reached, even when distracted by working activities
B 26-550 As "A" for 50-90% of persons being distracted
C 1-26 As "A" for less than 50% of persons being distracted
D 0.18-1 10-50% of persons aware of being tested perceive by smell that the Exposure Standard is being reached
E <0.18 As "D" for less than 10% of persons aware of being tested
. Odour Threshold Value: 47 ppm (detection), 71 ppm (recognition) IDLH Level: 150 ppm NOTE: Detector tubes for perchloroethylene, measuring in excess of 10 ppm, are commercially available. Exposure at or below the TLV-TWA is thought to prevent discomfort and subjective complaints arising during controlled human studies and prolonged industrial exposure to perchloroethylene at 100 ppm and 200 ppm. The STEL is recommended to minimise the potential of anaesthetic effects. Possible liver injury is unlikely as these values are thought to provide a wide margin of safety. On the basis of pharmacokinetic parameters and metabolic fate of perchloroethylene and in the absence of exposures which induce overt liver injury there is no expectation, by ACGIH, of a detectable increased risk of human liver cancer.

PERSONAL PROTECTION

EYE

· Safety glasses with side shields.
· Chemical goggles.
· Contact lenses may pose a special hazard; soft contact lenses may absorb and 
concentrate irritants. A written policy document, describing the wearing of lens or 
restrictions on use, should be created for each workplace or task. This should include a 
review of lens absorption and adsorption for the class of chemicals in use and an account 
of injury experience. Medical and first-aid personnel should be trained in their removal 
and suitable equipment should be readily available. In the event of chemical exposure, 
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens 
should be removed at the first signs of eye redness or irritation - lens should be 
removed in a clean environment only after workers have washed hands thoroughly. [CDC 
NIOSH Current Intelligence Bulletin 59].

HANDS/FEET

· No special equipment needed when handling small quantities.
· OTHERWISE:
· For potentially moderate exposures:
· Wear general protective gloves, eg. light weight rubber gloves.
· For potentially heavy exposures:
· Wear chemical protective gloves, eg. PVC. and safety footwear.

OTHER

No special equipment needed when handling small quantities.
OTHERWISE:
· Overalls.
· Skin cleansing cream.
· Eyewash unit.
· Do not spray on hot surfaces.

RESPIRATOR

Selection of the Class and Type of respirator will depend upon the level of breathing 
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined 
as the ratio of contaminant outside and inside the mask) may also be important.

Breathing Zone Level ppm (volume) Maximum Protection Factor Half-face Respirator Full-Face Respirator
1000 10 AX-AUS -
1000 50 - AX-AUS
5000 50 Airline * -
5000 100 - AX-2
10000 100 - AX-3
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand. The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required. For further information consult site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor.

ENGINEERING CONTROLS

General exhaust is adequate under normal conditions. If risk of overexposure exists, wear 
SAA approved respirator. Correct fit is essential to obtain adequate protection.
Provide adequate ventilation in warehouse or closed storage areas.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

Clear colourless spray with a chlorinated solvent odour; does not mix with water.

PHYSICAL PROPERTIES

Liquid.
Gas.
Does not mix with water.
Sinks in water.

 

Molecular Weight: Not Applicable Boiling Range (ºC): Not Available
Melting Range (ºC): Not Available Specific Gravity (water=1): 1.6 (concentrate)
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (ºC): Not Available
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (ºC): Not Available Decomposition Temp (ºC): Not Available
State: Liquid Viscosity: Not Available

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION

CONDITIONS CONTRIBUTING TO INSTABILITY

· Elevated temperatures.
· Presence of open flame.
· Product is considered stable.
· Hazardous polymerisation will not occur.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

Swallowing of the liquid may cause aspiration into the lungs with the risk of chemical 
pneumonitis; serious consequences may result. (ICSC13733).
Not normally a hazard due to physical form of product.
Considered an unlikely route of entry in commercial/industrial environments.

EYE

This material can cause eye irritation and damage in some persons.
Not considered to be a risk because of the extreme volatility of the gas.

SKIN

This material can cause inflammation of the skin on
contact in some persons.
The material may accentuate any pre-existing dermatitis condition.
Spray mist may produce discomfort.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may 
produce systemic injury with harmful effects. Examine the skin prior to the use of the 
material and ensure that any external damage is suitably protected.

INHALED

Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by 
sleepiness, reduced alertness, loss of reflexes, lack of co-ordination, and vertigo.
The vapour is discomforting.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Spray mist may produce discomfort.

CHRONIC HEALTH EFFECTS

Long-term exposure to the product is not thought to produce chronic effects adverse to 
the health (as classified by EC Directives using animal models); nevertheless exposure by 
all routes should be minimised as a matter of course.

TOXICITY AND IRRITATION

Not available. Refer to individual constituents.

TETRACHLOROETHYLENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of 
Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 2629 mg/kg Skin (rabbit): 810 mg/24h -SEVERE
Inhalation (man) LDLo: 2857 mg/kg Eye (rabbit): 162 mg -Mild
Inhalation (human) TCLo: 96 ppm/7 hrs
Inhalation (man) TCLo: 280 ppm/2 hrs
Inhalation (man) TCLo: 600 ppm/10 min
Inhalation (rat) LCLo: 34200 mg/m³/8 hr
The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin. Repeated exposures may produce severe ulceration. WARNING: This substance has been classified by the IARC as Group 2A: Probably Carcinogenic to Humans.

 

MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
_______________ ____________ __________ __________ __________
tetrachloroethylene IARC:2A NOHSC NTPB ILOEl
CARCINOGEN IARC: International Agency for Research on Cancer (IARC) Carcinogens: tetrachloroethylene Category: WARNING: This substance has been classified by the IARC as Group 2A: Probably Carcinogenic to Humans. CARCINOGEN NOHSC: Australia Exposure Standards - Carcinogens: tetrachloroethylene Carcinogen Category: 3 CARCINOGEN NTPB: US National Toxicology Program (NTP) 11th Report Part B. Reasonably Anticipated to be a Human Carcinogen: tetrachloroethylene Category: REPROTOXIN ILOEl: ILO Chemicals in the electronics industry that have toxic effects on reproduction: tetrachloroethylene

Section 12 - ECOLOGICAL INFORMATION

Marine Pollutant:Not Determined

DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:

TETRACHLOROETHYLENE:
Hazardous Air Pollutant:                                              Yes
log Kow (Sangster 1997):                                              3.4
Half- life Soil - High (hours):                                       8640
Half- life Soil - Low (hours):                                        4320
Half- life Air - High (hours):                                        3843
Half- life Air - Low (hours):                                         384
Half- life Surface water - High (hours):                              8640
Half- life Surface water - Low (hours):                               4320
Half- life Ground water - High (hours):                               17280
Half- life Ground water - Low (hours):                                8640
Aqueous biodegradation - Aerobic - High (hours):                      8640
Aqueous biodegradation - Aerobic - Low (hours):                       4320
Aqueous biodegradation - Anaerobic - High (hours):                    39672
Aqueous biodegradation - Anaerobic - Low (hours):                     2352
Aqueous biodegradation - Removal secondary treatment - High (hours):  86%
Photooxidation half- life air - High (hours):                         3843
Photooxidation half- life air - Low (hours):                          384

Do NOT allow product to come in contact with surface waters or to intertidal areas below 
the mean high water mark. Do not contaminate water when cleaning equipment or disposing 
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste 
sites.
Substances containing unsaturated carbons are ubiquitous in indoor environments. They 
result from many sources (see below). Most are reactive with environmental ozone and many 
produce stable products which are thought to adversely affect human health.The potential 
for surfaces in an enclosed space to facilitate reactions should be considered.

Source of unsaturated substances Unsaturated substances (Reactive Emissions) Major Stable Products produced following reaction with ozone.
Occupants (exhaled breath, ski oils, personal care products) Isoprene, nitric oxide, squalene, unsaturated sterols, oleic acid and other unsaturated fatty acids, unsaturated oxidation products Methacrolein, methyl vinyl ketone, nitrogen dioxide, acetone, 6MHQ, geranyl acetone, 4OPA, formaldehyde, nonanol, decanal, 9-oxo-nonanoic acid, azelaic acid, nonanoic acid.
Soft woods, wood flooring, including cypress, cedar and silver fir boards, houseplants Isoprene, limonene, alpha-pinene, other terpenes and sesquiterpenes Formaldehyde, 4-AMC, pinoaldehyde, pinic acid, pinonic acid, formic acid, methacrolein, methyl vinyl ketone, SOAs including ultrafine particles
Carpets and carpet backing 4-Phenylcyclohexene, 4-vinylcyclohexene, styrene, 2-ethylhexyl acrylate, unsaturated fatty acids and esters Formaldehyde, acetaldehyde, benzaldehyde, hexanal, nonanal, 2-nonenal
Linoleum and paints/polishes containing linseed oil Linoleic acid, linolenic acid Propanal, hexanal, nonanal, 2-heptenal, 2-nonenal, 2-decenal, 1-pentene-3- one, propionic acid, n-butyric acid
Latex paint Residual monomers Formaldehyde
Certain cleaning products, polishes, waxes, air fresheners Limonene, alpha-pinene, terpinolene, alpha-terpineol, linalool, linalyl acetate and other terpenoids, longifolene and other sesquiterpenes Formaldehyde, acetaldehyde, glycoaldehyde, formic acid, acetic acid, hydrogen and organic peroxides, acetone, benzaldehyde, 4-hydroxy-4-methyl-5-hexen-1-al, 5- ethenyl-dihydro-5-methyl-2(3H)-furanone, 4-AMC, SOAs including ultrafine particles
Natural rubber adhesive Isoprene, terpenes Formaldehyde, methacrolein, methyl vinyl ketone
Photocopier toner, printed paper, styrene polymers Styrene Formaldehyde, benzaldehyde
Environmental tobacco smoke Styrene, acrolein, nicotine Formaldehyde, benzaldehyde, hexanal, glyoxal, N-methylformamide, nicotinaldehyde, cotinine
Soiled clothing, fabrics, bedding Squalene, unsaturated sterols, oleic acid and other saturated fatty acids Acetone, geranyl acetone, 6MHO, 40PA, formaldehyde, nonanal, decanal, 9- oxo-nonanoic acid, azelaic acid, nonanoic acid
Soiled particle filters Unsaturated fatty acids from plant waxes, leaf litter, and other vegetative debris; soot; diesel particles Formaldehyde, nonanal, and other aldehydes; azelaic acid; nonanoic acid; 9-oxo-nonanoic acid and other oxo-acids; compounds with mixed functional groups (=O, -OH, and -COOH)
Ventilation ducts and duct liners Unsaturated fatty acids and esters, unsaturated oils, neoprene C5 to C10 aldehydes
"Urban grime" Polycyclic aromatic hydrocarbons Oxidized polycyclic aromatic hydrocarbons
Perfumes, colognes, essential oils (e.g. lavender, eucalyptus, tea tree) Limonene, alpha-pinene, linalool, linalyl acetate, terpinene-4-ol, gamma- terpinene Formaldehyde, 4-AMC, acetone, 4-hydroxy-4-methyl-5-hexen-1-al, 5-ethenyl- dihydro-5-methyl-2(3H) furanone, SOAs including ultrafine particles
Overall home emissions Limonene, alpha-pinene, styrene Formaldehyde, 4-AMC, pinonaldehyde, acetone, pinic acid, pinonic acid, formic acid, benzaldehyde, SOAs including ultrafine particles
Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA, 4-oxopentanal, SOA, Secondary Organic Aerosols Reference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006. DO NOT discharge into sewer or waterways. log Koc: 2.38-2.97 Koc: 209-1685 Half-life (hr) H2O surface water: 26.4-2664 Henry's atm m³ /mol: 1.49E-02 BOD 5 if unstated: 0.06 COD: 0.39 BCF: 38.9-226 Log BCF: 1.59 Toxicity Fish: LC50(96)16-20mg/L Toxicity invertebrate: LC50(48)9.32mg/L Bioacculmulation: not sig Degradation Biological: little processes Abiotic: some aq hydro,v slowRxnOH*

Section 13 - DISPOSAL CONSIDERATIONS

· Consult State Land Waste Management Authority for disposal.
· Discharge contents of damaged aerosol cans at an approved site.
· Allow small quantities to evaporate.
· DO NOT incinerate or puncture aerosol cans.
· Bury residues and emptied aerosol cans at an approved site.

Section 14 - TRANSPORTATION INFORMATION

Labels Required: NON-FLAMMABLE COMPRESSED GAS
HAZCHEM: 2Y

UNDG:
Dangerous Goods Class: 2.2 Subrisk: None
UN Number: 1950 Packing Group: None
Shipping Name:AEROSOLS

Air Transport IATA:

ICAO/IATA Class: 2.2 ICAO/IATA Subrisk: None
UN/ID Number: 1950 Packing Group: None
Special provisions: A98 A145 A153
Shipping Name: AEROSOLS, NON-FLAMMABLE

Maritime Transport IMDG:

IMDG Class: 2.2 IMDG Subrisk: SP63
UN Number: 1950 Packing Group: None
EMS Number: F-D,S-U Special provisions: 63 190 277 327 959
Limited Quantities: See SP277 Marine Pollutant: Not Determined
Shipping Name: AEROSOLS

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE: None

REGULATIONS

0890 108 93 - Wurth Multi Clean NF - Non Flammable (CAS: None):
No regulations applicable

tetrachloroethylene (CAS: 127-18-4) is found on the following regulatory lists;
    Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - organic compounds)
    Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm (Aquatic 
habitat)
    Australia - Australian Capital Territory Environment Protection Regulation Ecosystem maintenance - Organic chemicals - Non-pesticide anthropogenic organics
    Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Domestic water quality
    Australia Exposure Standards
    Australia Hazardous Substances
    Australia High Volume Industrial Chemical List (HVICL)
    Australia Inventory of Chemical Substances (AICS)
    Australia National Pollutant Inventory
    Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
    Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
    Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 2
    Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
    Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
    GESAMP/EHS Composite List of Hazard Profiles - Hazard evaluation of substances transported by ships
    IMO IBC Code Chapter 17: Summary of minimum requirements
    IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
    International Agency for Research on Cancer (IARC) Carcinogens
    OECD Representative List of High Production Volume (HPV) Chemicals
    WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water

Section 16 - OTHER INFORMATION

REPRODUCTIVE HEALTH GUIDELINES

Established occupational exposure limits frequently do not take into consideration 
reproductive end points that are clearly below the thresholds for other toxic effects. 
Occupational reproductive guidelines (ORGs) have been suggested as an additional 
standard. These have been established after a literature search for the reproductive no-
observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level 
(LOAEL). In addition the US EPA's procedures for risk assessment for hazard 
identification and dose-response assessment as applied by NIOSH were used in the creation 
of such limits. Uncertainty factors (UFs) have also been incorporated.
Ingredient                 ORG                 UF      Endpoi  CR      Adeq
                                                       nt              TLV
tetrachloroethylene        11.87 mg/m3         100     R       20      -
These exposure guidelines have been derived from a screening level of risk assessment and 
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time-
weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).

 

Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.

 

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk
Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Scale of use, frequency of use and current or available engineering controls must be
considered.

 

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.

 

Issue Date: 28-May-2008

Print Date: 28-May-2008